Abstract
The C-S bond is formed to a greater extent than the C-O bond in the transition state of the [4+2] cycloaddition of S02 to dimethylidenecyclohexane (see scheme). Both deuterium isotope effects and quantum calculations lead to this conclusion.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 3924-3927 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 42 |
| Issue number | 33 |
| DOIs | |
| State | Published - Aug 25 2003 |
| Externally published | Yes |
Keywords
- Ab initio calculations
- Cycloaddition
- Heterocycles
- Isotope effects
- Sulfur dioxide
Fingerprint
Dive into the research topics of 'Equilibrium and kinetic deuterium isotope effects on the hetero-Diels-Alder addition of sulfur dioxide'. Together they form a unique fingerprint.Cite this
- APA
- Standard
- Harvard
- Vancouver
- Author
- BIBTEX
- RIS