Equilibrium and kinetic deuterium isotope effects on the hetero-Diels-Alder addition of sulfur dioxide

Frédéric Monnat, Pierre Vogel, Ruben Meana Paneda, José A. Sordo

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The C-S bond is formed to a greater extent than the C-O bond in the transition state of the [4+2] cycloaddition of S02 to dimethylidenecyclohexane (see scheme). Both deuterium isotope effects and quantum calculations lead to this conclusion.

Original languageEnglish (US)
Pages (from-to)3924-3927
Number of pages4
JournalAngewandte Chemie - International Edition
Volume42
Issue number33
DOIs
StatePublished - Aug 25 2003

Keywords

  • Ab initio calculations
  • Cycloaddition
  • Heterocycles
  • Isotope effects
  • Sulfur dioxide

Fingerprint Dive into the research topics of 'Equilibrium and kinetic deuterium isotope effects on the hetero-Diels-Alder addition of sulfur dioxide'. Together they form a unique fingerprint.

Cite this