Enzyme Substrate Complex of the H200C Variant of Homoprotocatechuate 2,3-Dioxygenase: Mössbauer and Computational Studies

Keyphrases

• Computational Study 100%
• Mssbauer 100%
• Homoprotocatechuate 2,3-dioxygenase 100%
• Enzyme-substrate Complex 100%
• Zero-field Splitting 75%
• Fe(II) 75%
• Active Sites 50%
• Electric Field Gradient 50%
• Splitting Tensor 50%
• High Spin 50%
• Second Sphere 50%
• Catalytic Processes 25%
• Electronic Structure 25%
• Magnetization 25%
• Aromatic Ring 25%
• Symmetry Axis 25%
• 57Fe 25%
• DFT Calculations 25%
• Reaction Cycle 25%
• Retardation 25%
• Electric Field Gradient Tensor 25%
• Spin Hamiltonian 25%
• Spectroscopic Characterization 25%
• Relative Orientation 25%
• Active Site Structure 25%
• Integer Spin 25%
• Alpha Value 25%
• Enzyme Substrates 25%
• Crystal Field Theory 25%
• Hamiltonian Analysis 25%
• Mssbauer Spectroscopy 25%
• Low Symmetry 25%
• CASSCF 25%

Chemistry

• Dioxygenases 100%
• Zero Field Splitting 75%
• Electric Field Gradient 75%
• Catalysis 50%
• Density Functional Theory 50%
• Electronic State 25%
• CASSCF Calculation 25%
• Crystal Field 25%
• Spin Hamiltonian 25%
• Aromatic Structure 25%
• Spectroscopy 25%
• Field Theory 25%