Abstract
We report the transfer of entropic chain length effects into the realm of supramolecular chemistry and thereby demonstrate a macromolecular method to tune the reaction equilibria of hydrogen bonding motifs via the application of substituents of differing lengths and masses while not altering the actual recognition units to achieve a difference in the degree of association. The supramolecular adducts are characterized via temperature-dependent nuclear magnetic resonance (NMR) spectroscopy. (Figure Presented).
| Original language | English (US) |
|---|---|
| Pages (from-to) | 774-777 |
| Number of pages | 4 |
| Journal | ACS Macro Letters |
| Volume | 4 |
| Issue number | 7 |
| DOIs | |
| State | Published - Jul 21 2015 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2015 American Chemical Society.
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