Abstract
We report the transfer of entropic chain length effects into the realm of supramolecular chemistry and thereby demonstrate a macromolecular method to tune the reaction equilibria of hydrogen bonding motifs via the application of substituents of differing lengths and masses while not altering the actual recognition units to achieve a difference in the degree of association. The supramolecular adducts are characterized via temperature-dependent nuclear magnetic resonance (NMR) spectroscopy. (Figure Presented).
Original language | English (US) |
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Pages (from-to) | 774-777 |
Number of pages | 4 |
Journal | ACS Macro Letters |
Volume | 4 |
Issue number | 7 |
DOIs | |
State | Published - Jul 21 2015 |
Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2015 American Chemical Society.