Abstract
Several new energetic ethyl ethers of 1,2,4,5-tetrazine have been synthesized. These molecules display good thermal stability, good oxygen balance, and high densities. Included in these studies are a 2,2,2-trinitroethoxy 1,2,4,5-tetrazine and two fluorodinitroethoxy 1,2,4,5-tetrazines. One of these compounds was converted into the di-N-oxide derivative. The sensitivity of these materials towards destructive stimuli was determined, and overall the materials show promising energetic performance properties.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 8666-8669 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 55 |
| Issue number | 30 |
| DOIs | |
| State | Published - Jul 18 2016 |
Bibliographical note
Publisher Copyright:© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Keywords
- energetic materials
- fluorine
- heterocycles
- oxidation
- structure determination
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