TY - JOUR
T1 - Energetic Trinitro- and Fluorodinitroethyl Ethers of 1,2,4,5-Tetrazines
AU - Chavez, David E.
AU - Parrish, Damon A.
AU - Mitchell, Lauren
PY - 2016/1/1
Y1 - 2016/1/1
N2 - Several new energetic ethyl ethers of 1,2,4,5-tetrazine have been synthesized. These molecules display good thermal stability, good oxygen balance, and high densities. Included in these studies are a 2,2,2-trinitroethoxy 1,2,4,5-tetrazine and two fluorodinitroethoxy 1,2,4,5-tetrazines. One of these compounds was converted into the di-N-oxide derivative. The sensitivity of these materials towards destructive stimuli was determined, and overall the materials show promising energetic performance properties.
AB - Several new energetic ethyl ethers of 1,2,4,5-tetrazine have been synthesized. These molecules display good thermal stability, good oxygen balance, and high densities. Included in these studies are a 2,2,2-trinitroethoxy 1,2,4,5-tetrazine and two fluorodinitroethoxy 1,2,4,5-tetrazines. One of these compounds was converted into the di-N-oxide derivative. The sensitivity of these materials towards destructive stimuli was determined, and overall the materials show promising energetic performance properties.
KW - energetic materials
KW - fluorine
KW - heterocycles
KW - oxidation
KW - structure determination
UR - http://www.scopus.com/inward/record.url?scp=84973544448&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84973544448&partnerID=8YFLogxK
U2 - 10.1002/anie.201604115
DO - 10.1002/anie.201604115
M3 - Article
C2 - 27273564
AN - SCOPUS:84973544448
VL - 55
SP - 8666
EP - 8669
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 30
ER -