Endo-effect-driven regioselectivity in the cyclopalladation of (S)-2-tert-butyl-4-phenyl-2-oxazoline

Keyphrases

• Tert-butyl 100%
• Regioselectivity 100%
• Phenyl 100%
• 2-oxazoline 100%
• Cyclopalladation 100%
• PPh3 100%
• Palladacycle 66%
• Oxazoline 66%
• Dimeric Complex 66%
• Solid State 33%
• Propeller 33%
• Acetone 33%
• Butyl 33%
• Single Point 33%
• Acetonitrile 33%
• NMR Data 33%
• Coupled Cluster Calculations 33%
• Acetic Acid 33%
• X-ray Crystal Structure 33%
• Lithium Chloride 33%
• Palladium 33%
• Isomeric Compounds 33%
• Palladium Acetate 33%
• Twisted Conformation 33%
• Ab Initio Quantum Chemical Calculation 33%
• Puckered Structure 33%
• Light Atoms 33%
• LANL2DZ 33%
• In(III) 33%
• Heterocycles 33%
• Double Excitation 33%
• Chiral Configuration 33%

Chemistry

• Regioselectivity 100%
• Oxazoline 100%
• Palladium 50%
• Crystal Structure 25%
• Møller-Plesset Perturbation Theory 25%
• Quantum Chemical Calculations 25%
• Coupled Cluster Theory 25%
• Acetic Acid 25%
• NMR Data 25%
• Heterocyclic Compound 25%
• Acetone 25%
• Acetonitrile 25%
• Acetate 25%
• Ammonia 25%