Elucidation of the reaction mechanism for the palladium-catalyzed synthesis of vinyl acetate

Dario Stacchiola; Florencia Calaza; Luke Burkholder; Alan W. Schwabacher; Matthew Neurock; Wilfred T. Tysoe

doi:10.1002/anie.200500782

Elucidation of the reaction mechanism for the palladium-catalyzed synthesis of vinyl acetate

Dario Stacchiola, Florencia Calaza, Luke Burkholder, Alan W. Schwabacher, Matthew Neurock, Wilfred T. Tysoe

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

(Chemical Equation Presented) Finding the right pathway: Reaction of isotopomers of ethylene with acetate species (see scheme) adsorbed on a Pd(111) surface in ultrahigh vacuum has shown that vinyl acetate is produced by insertion of ethylene into the acetate species to form an acetoxyethyl intermediate, which decomposes by β-hydride elimination to yield vinyl acetate.

Original language	English (US)
Pages (from-to)	4572-4574
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	29
DOIs	https://doi.org/10.1002/anie.200500782
State	Published - Jul 18 2005

Keywords

IR spectroscopy
Isotopes
Palladium
Reaction mechanisms
Surface chemistry

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10.1002/anie.200500782

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abstract = "(Chemical Equation Presented) Finding the right pathway: Reaction of isotopomers of ethylene with acetate species (see scheme) adsorbed on a Pd(111) surface in ultrahigh vacuum has shown that vinyl acetate is produced by insertion of ethylene into the acetate species to form an acetoxyethyl intermediate, which decomposes by β-hydride elimination to yield vinyl acetate.",

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AU - Calaza, Florencia

AU - Burkholder, Luke

AU - Schwabacher, Alan W.

AU - Neurock, Matthew

AU - Tysoe, Wilfred T.

PY - 2005/7/18

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KW - IR spectroscopy

KW - Isotopes

KW - Palladium

KW - Reaction mechanisms

KW - Surface chemistry

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JF - Angewandte Chemie - International Edition

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Elucidation of the reaction mechanism for the palladium-catalyzed synthesis of vinyl acetate

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