Elucidation of tetraboric acid with a new borate fundamental building block in a chiral uranyl fluoroborate

Shuao Wang; T. Gannon Parker; Daniel J. Grant; Juan Diwu; Evgeny V. Alekseev; Wulf Depmeier; Laura Gagliardi; Thomas E. Albrecht-Schmitt

doi:10.1021/ic300741s

Elucidation of tetraboric acid with a new borate fundamental building block in a chiral uranyl fluoroborate

Shuao Wang, T. Gannon Parker, Daniel J. Grant, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Laura Gagliardi, Thomas E. Albrecht-Schmitt

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

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Abstract

A new neutral borate species, H ₂B ₄O ₇ (also known as tetraboric acid), with a one-dimensional chain structure, is found in the interlayer spacing in Rb ₂[(UO ₂) ₂B ₈O ₁₂F ₆]·H ₂B ₄O ₇ (RbUBOF-2) derived from boric acid flux reaction of uranyl(VI) nitrate with RbBF ₄. This new form of tetraboric acid possesses a novel borate fundamental building block with the symbol 4Δ: 〈3Δ〉Δ.

Original language	English (US)
Pages (from-to)	11211-11213
Number of pages	3
Journal	Inorganic chemistry
Volume	51
Issue number	21
DOIs	https://doi.org/10.1021/ic300741s
State	Published - Nov 5 2012

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title = "Elucidation of tetraboric acid with a new borate fundamental building block in a chiral uranyl fluoroborate",

abstract = "A new neutral borate species, H 2B 4O 7 (also known as tetraboric acid), with a one-dimensional chain structure, is found in the interlayer spacing in Rb 2[(UO 2) 2B 8O 12F 6]·H 2B 4O 7 (RbUBOF-2) derived from boric acid flux reaction of uranyl(VI) nitrate with RbBF 4. This new form of tetraboric acid possesses a novel borate fundamental building block with the symbol 4Δ: 〈3Δ〉Δ.",

author = "Shuao Wang and Parker, {T. Gannon} and Grant, {Daniel J.} and Juan Diwu and Alekseev, {Evgeny V.} and Wulf Depmeier and Laura Gagliardi and Albrecht-Schmitt, {Thomas E.}",

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T1 - Elucidation of tetraboric acid with a new borate fundamental building block in a chiral uranyl fluoroborate

AU - Wang, Shuao

AU - Parker, T. Gannon

AU - Grant, Daniel J.

AU - Diwu, Juan

AU - Alekseev, Evgeny V.

AU - Depmeier, Wulf

AU - Gagliardi, Laura

AU - Albrecht-Schmitt, Thomas E.

PY - 2012/11/5

Y1 - 2012/11/5

N2 - A new neutral borate species, H 2B 4O 7 (also known as tetraboric acid), with a one-dimensional chain structure, is found in the interlayer spacing in Rb 2[(UO 2) 2B 8O 12F 6]·H 2B 4O 7 (RbUBOF-2) derived from boric acid flux reaction of uranyl(VI) nitrate with RbBF 4. This new form of tetraboric acid possesses a novel borate fundamental building block with the symbol 4Δ: 〈3Δ〉Δ.

AB - A new neutral borate species, H 2B 4O 7 (also known as tetraboric acid), with a one-dimensional chain structure, is found in the interlayer spacing in Rb 2[(UO 2) 2B 8O 12F 6]·H 2B 4O 7 (RbUBOF-2) derived from boric acid flux reaction of uranyl(VI) nitrate with RbBF 4. This new form of tetraboric acid possesses a novel borate fundamental building block with the symbol 4Δ: 〈3Δ〉Δ.

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Elucidation of tetraboric acid with a new borate fundamental building block in a chiral uranyl fluoroborate

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