Electrografted monolayer based on a naphthalene diimide-ruthenium terpyridine complex dyad: Efficient creation of large-area molecular junctions with high current densities

Denis Frath; Van Quyen Nguyen; Frédéric Lafolet; Pascal Martin; Jean Christophe Lacroix

doi:10.1039/c7cc04972b

Electrografted monolayer based on a naphthalene diimide-ruthenium terpyridine complex dyad: Efficient creation of large-area molecular junctions with high current densities

Denis Frath
, Van Quyen Nguyen
, Frédéric Lafolet
, Pascal Martin
, Jean Christophe Lacroix

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

An electron donor-acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of operating devices.

Original language	English (US)
Pages (from-to)	10997-11000
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	80
DOIs	https://doi.org/10.1039/c7cc04972b
State	Published - 2017
Externally published	Yes

Bibliographical note

Funding Information:
We thank the Centre National de la Recherche Scientifique, and Agence Nationale de la Recherche (ANR-15-CE09 0001-01) for their financial support. We also warmly thank B. Lemarque and P. Decorse for XPS analyses and discussions.

Publisher Copyright:
© 2017 The Royal Society of Chemistry.

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10.1039/c7cc04972b

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Electrografted monolayer based on a naphthalene diimide-ruthenium terpyridine complex dyad: Efficient creation of large-area molecular junctions with high current densities. / Frath, Denis; Nguyen, Van Quyen; Lafolet, Frédéric et al.
In: Chemical Communications, Vol. 53, No. 80, 2017, p. 10997-11000.

Research output: Contribution to journal › Article › peer-review

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abstract = "An electron donor-acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of operating devices.",

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AU - Lafolet, Frédéric

AU - Martin, Pascal

AU - Lacroix, Jean Christophe

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AB - An electron donor-acceptor dyad has been designed for the creation of large-area molecular junctions (MJ). Diazonium cation electrografting was used to form well controlled monolayers. The robustness of the monolayer enabled the creation of MJs using direct top-coat evaporation with a high yield of operating devices.

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Electrografted monolayer based on a naphthalene diimide-ruthenium terpyridine complex dyad: Efficient creation of large-area molecular junctions with high current densities

Abstract

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