Efficient dispersion of crude oil by blends of food-grade surfactants: Toward greener oil-spill treatments

David A. Riehm; John E. Neilsen; Geoffrey D. Bothun; Vijay T. John; Srinivasa R. Raghavan; Alon V. McCormick

doi:10.1016/j.marpolbul.2015.11.012

Efficient dispersion of crude oil by blends of food-grade surfactants: Toward greener oil-spill treatments

David A. Riehm, John E. Neilsen, Geoffrey D. Bothun, Vijay T. John, Srinivasa R. Raghavan, Alon V. McCormick

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Effectiveness of oil spill dispersants containing lecithin/Tween 80 (L/T) blends in ethanol was measured as a function of L:T ratio, surfactant:solvent ratio, solvent composition, and dispersant:oil ratio (DOR) using baffled flask dispersion effectiveness tests. Optimal L:T ratios are between 60:40 and 80:20 (w/w); at higher L:T ratios, effectiveness is limited by high interfacial tension, while at lower L:T ratios, insufficient lecithin is present to form a well-packed monolayer at an oil-water interface. These optimal L:T ratios retain high effectiveness at low DOR: 80:20 (w/w) L:T dispersant is 89% effective at 1:25 DOR (v/v) and 77% effective at 1:100 DOR (v/v). Increasing surfactant:solvent ratio increases dispersant effectiveness even when DOR is proportionally reduced to keep total surfactant concentration dosed into the oil constant. Replacing some of the ethanol with octane or octanol also increases dispersant effectiveness, suggesting that ethanol's hydrophilicity lowers dispersant-oil miscibility, and that more hydrophobic solvents would increase effectiveness.

Original language	English (US)
Pages (from-to)	92-97
Number of pages	6
Journal	Marine Pollution Bulletin
Volume	101
Issue number	1
DOIs	https://doi.org/10.1016/j.marpolbul.2015.11.012
State	Published - 2015

Bibliographical note

Funding Information:
The authors are grateful to undergraduate researchers Sarah Downey and Prakash Paul for assisting David Riehm by running dispersion effectiveness tests, to Dr. Edith Holder of the USEPA and Drs. Tim Nedwed and Tom Coolbaugh of ExxonMobil for helpful discussions, and to the Mkhoyan group for the use of their UV–Vis spectrophotometer. This work was supported in part by a grant from the Gulf of Mexico Research Initiative (GoMRI) (Consortium for Ocean Leadership Grant SA 12-05/GoMRI-002 ) to the Consortium for the Molecular Engineering of Dispersants (C-MEDS). A digital version of the dataset supporting this paper is available through the Gulf of Mexico Research Initiative Information and Data Cooperative (GRIIDC) at https://data.gulfresearchinitiative.org/ .

Publisher Copyright:
© 2015 Elsevier Ltd.

Keywords

Crude oil
Dispersant
Lecithin
Oil spill
Tween 80

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10.1016/j.marpolbul.2015.11.012

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title = "Efficient dispersion of crude oil by blends of food-grade surfactants: Toward greener oil-spill treatments",

abstract = "Effectiveness of oil spill dispersants containing lecithin/Tween 80 (L/T) blends in ethanol was measured as a function of L:T ratio, surfactant:solvent ratio, solvent composition, and dispersant:oil ratio (DOR) using baffled flask dispersion effectiveness tests. Optimal L:T ratios are between 60:40 and 80:20 (w/w); at higher L:T ratios, effectiveness is limited by high interfacial tension, while at lower L:T ratios, insufficient lecithin is present to form a well-packed monolayer at an oil-water interface. These optimal L:T ratios retain high effectiveness at low DOR: 80:20 (w/w) L:T dispersant is 89% effective at 1:25 DOR (v/v) and 77% effective at 1:100 DOR (v/v). Increasing surfactant:solvent ratio increases dispersant effectiveness even when DOR is proportionally reduced to keep total surfactant concentration dosed into the oil constant. Replacing some of the ethanol with octane or octanol also increases dispersant effectiveness, suggesting that ethanol's hydrophilicity lowers dispersant-oil miscibility, and that more hydrophobic solvents would increase effectiveness.",

keywords = "Crude oil, Dispersant, Lecithin, Oil spill, Tween 80",

author = "Riehm, {David A.} and Neilsen, {John E.} and Bothun, {Geoffrey D.} and John, {Vijay T.} and Raghavan, {Srinivasa R.} and McCormick, {Alon V.}",

note = "Funding Information: The authors are grateful to undergraduate researchers Sarah Downey and Prakash Paul for assisting David Riehm by running dispersion effectiveness tests, to Dr. Edith Holder of the USEPA and Drs. Tim Nedwed and Tom Coolbaugh of ExxonMobil for helpful discussions, and to the Mkhoyan group for the use of their UV–Vis spectrophotometer. This work was supported in part by a grant from the Gulf of Mexico Research Initiative (GoMRI) (Consortium for Ocean Leadership Grant SA 12-05/GoMRI-002 ) to the Consortium for the Molecular Engineering of Dispersants (C-MEDS). A digital version of the dataset supporting this paper is available through the Gulf of Mexico Research Initiative Information and Data Cooperative (GRIIDC) at https://data.gulfresearchinitiative.org/ . Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd.",

year = "2015",

doi = "10.1016/j.marpolbul.2015.11.012",

language = "English (US)",

volume = "101",

pages = "92--97",

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T1 - Efficient dispersion of crude oil by blends of food-grade surfactants

T2 - Toward greener oil-spill treatments

AU - Riehm, David A.

AU - Neilsen, John E.

AU - Bothun, Geoffrey D.

AU - John, Vijay T.

AU - Raghavan, Srinivasa R.

AU - McCormick, Alon V.

N1 - Funding Information: The authors are grateful to undergraduate researchers Sarah Downey and Prakash Paul for assisting David Riehm by running dispersion effectiveness tests, to Dr. Edith Holder of the USEPA and Drs. Tim Nedwed and Tom Coolbaugh of ExxonMobil for helpful discussions, and to the Mkhoyan group for the use of their UV–Vis spectrophotometer. This work was supported in part by a grant from the Gulf of Mexico Research Initiative (GoMRI) (Consortium for Ocean Leadership Grant SA 12-05/GoMRI-002 ) to the Consortium for the Molecular Engineering of Dispersants (C-MEDS). A digital version of the dataset supporting this paper is available through the Gulf of Mexico Research Initiative Information and Data Cooperative (GRIIDC) at https://data.gulfresearchinitiative.org/ . Publisher Copyright: © 2015 Elsevier Ltd.

PY - 2015

Y1 - 2015

N2 - Effectiveness of oil spill dispersants containing lecithin/Tween 80 (L/T) blends in ethanol was measured as a function of L:T ratio, surfactant:solvent ratio, solvent composition, and dispersant:oil ratio (DOR) using baffled flask dispersion effectiveness tests. Optimal L:T ratios are between 60:40 and 80:20 (w/w); at higher L:T ratios, effectiveness is limited by high interfacial tension, while at lower L:T ratios, insufficient lecithin is present to form a well-packed monolayer at an oil-water interface. These optimal L:T ratios retain high effectiveness at low DOR: 80:20 (w/w) L:T dispersant is 89% effective at 1:25 DOR (v/v) and 77% effective at 1:100 DOR (v/v). Increasing surfactant:solvent ratio increases dispersant effectiveness even when DOR is proportionally reduced to keep total surfactant concentration dosed into the oil constant. Replacing some of the ethanol with octane or octanol also increases dispersant effectiveness, suggesting that ethanol's hydrophilicity lowers dispersant-oil miscibility, and that more hydrophobic solvents would increase effectiveness.

AB - Effectiveness of oil spill dispersants containing lecithin/Tween 80 (L/T) blends in ethanol was measured as a function of L:T ratio, surfactant:solvent ratio, solvent composition, and dispersant:oil ratio (DOR) using baffled flask dispersion effectiveness tests. Optimal L:T ratios are between 60:40 and 80:20 (w/w); at higher L:T ratios, effectiveness is limited by high interfacial tension, while at lower L:T ratios, insufficient lecithin is present to form a well-packed monolayer at an oil-water interface. These optimal L:T ratios retain high effectiveness at low DOR: 80:20 (w/w) L:T dispersant is 89% effective at 1:25 DOR (v/v) and 77% effective at 1:100 DOR (v/v). Increasing surfactant:solvent ratio increases dispersant effectiveness even when DOR is proportionally reduced to keep total surfactant concentration dosed into the oil constant. Replacing some of the ethanol with octane or octanol also increases dispersant effectiveness, suggesting that ethanol's hydrophilicity lowers dispersant-oil miscibility, and that more hydrophobic solvents would increase effectiveness.

KW - Crude oil

KW - Dispersant

KW - Lecithin

KW - Oil spill

KW - Tween 80

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DO - 10.1016/j.marpolbul.2015.11.012

M3 - Article

C2 - 26589641

AN - SCOPUS:84982840989

VL - 101

SP - 92

EP - 97

JO - Marine Pollution Bulletin

JF - Marine Pollution Bulletin

SN - 0025-326X

IS - 1

ER -

Efficient dispersion of crude oil by blends of food-grade surfactants: Toward greener oil-spill treatments

Abstract

Bibliographical note

Keywords

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