Effects of hydrogen bonding on the ring breathing mode of pyridine in pyridine/chloroform and pyridine/bromoform systems

Haiyan Fan; C. Diane Moliva A.; Jeffrey K. Eliason; Jason L. Olson; Daniel D. Green; M. W. Gealy; Darin J. Ulness

doi:10.1016/j.cplett.2009.07.092

Effects of hydrogen bonding on the ring breathing mode of pyridine in pyridine/chloroform and pyridine/bromoform systems

Haiyan Fan, C. Diane Moliva A., Jeffrey K. Eliason, Jason L. Olson, Daniel D. Green, M. W. Gealy, Darin J. Ulness

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Hydrogen bonding between pyridine and chloroform as well as pyridine and bromoform is studied using noisy light-based coherent anti-Stokes Raman scattering (I⁽²⁾CARS). A blue-shift in the ring breathing mode of pyridine is observed when a hydrogen bond complex is formed between the nitrogen on pyridine and the hydrogen from the donor molecule. The formation of the hydrogen bond between haloforms and pyridine is very weak and does not result in an independent peak. Nonetheless, data analysis allows for identification of a small blue-shift of the hydrogen bonded complex.

Original language	English (US)
Pages (from-to)	43-46
Number of pages	4
Journal	Chemical Physics Letters
Volume	479
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2009.07.092
State	Published - Sep 7 2009

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title = "Effects of hydrogen bonding on the ring breathing mode of pyridine in pyridine/chloroform and pyridine/bromoform systems",

abstract = "Hydrogen bonding between pyridine and chloroform as well as pyridine and bromoform is studied using noisy light-based coherent anti-Stokes Raman scattering (I(2)CARS). A blue-shift in the ring breathing mode of pyridine is observed when a hydrogen bond complex is formed between the nitrogen on pyridine and the hydrogen from the donor molecule. The formation of the hydrogen bond between haloforms and pyridine is very weak and does not result in an independent peak. Nonetheless, data analysis allows for identification of a small blue-shift of the hydrogen bonded complex.",

author = "Haiyan Fan and {Diane Moliva A.}, C. and Eliason, {Jeffrey K.} and Olson, {Jason L.} and Green, {Daniel D.} and Gealy, {M. W.} and Ulness, {Darin J.}",

year = "2009",

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doi = "10.1016/j.cplett.2009.07.092",

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T1 - Effects of hydrogen bonding on the ring breathing mode of pyridine in pyridine/chloroform and pyridine/bromoform systems

AU - Fan, Haiyan

AU - Diane Moliva A., C.

AU - Eliason, Jeffrey K.

AU - Olson, Jason L.

AU - Green, Daniel D.

AU - Gealy, M. W.

AU - Ulness, Darin J.

PY - 2009/9/7

Y1 - 2009/9/7

N2 - Hydrogen bonding between pyridine and chloroform as well as pyridine and bromoform is studied using noisy light-based coherent anti-Stokes Raman scattering (I(2)CARS). A blue-shift in the ring breathing mode of pyridine is observed when a hydrogen bond complex is formed between the nitrogen on pyridine and the hydrogen from the donor molecule. The formation of the hydrogen bond between haloforms and pyridine is very weak and does not result in an independent peak. Nonetheless, data analysis allows for identification of a small blue-shift of the hydrogen bonded complex.

AB - Hydrogen bonding between pyridine and chloroform as well as pyridine and bromoform is studied using noisy light-based coherent anti-Stokes Raman scattering (I(2)CARS). A blue-shift in the ring breathing mode of pyridine is observed when a hydrogen bond complex is formed between the nitrogen on pyridine and the hydrogen from the donor molecule. The formation of the hydrogen bond between haloforms and pyridine is very weak and does not result in an independent peak. Nonetheless, data analysis allows for identification of a small blue-shift of the hydrogen bonded complex.

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DO - 10.1016/j.cplett.2009.07.092

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SP - 43

EP - 46

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Effects of hydrogen bonding on the ring breathing mode of pyridine in pyridine/chloroform and pyridine/bromoform systems

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