Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers

Colin O. Hayes; Peng Hao Chen; R. Paxton Thedford; Christopher J. Ellison; Guangbin Dong; C. Grant Willson

doi:10.1021/acs.macromol.6b00316

Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers

Colin O. Hayes
, Peng Hao Chen
, R. Paxton Thedford
, Christopher J. Ellison
, Guangbin Dong
, C. Grant Willson

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.

Original language	English (US)
Pages (from-to)	3706-3715
Number of pages	10
Journal	Macromolecules
Volume	49
Issue number	10
DOIs	https://doi.org/10.1021/acs.macromol.6b00316
State	Published - May 24 2016

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© 2016 American Chemical Society.

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title = "Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers",

abstract = "The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.",

author = "Hayes, \{Colin O.\} and Chen, \{Peng Hao\} and Thedford, \{R. Paxton\} and Ellison, \{Christopher J.\} and Guangbin Dong and \{Grant Willson\}, C.",

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doi = "10.1021/acs.macromol.6b00316",

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AU - Hayes, Colin O.

AU - Chen, Peng Hao

AU - Thedford, R. Paxton

AU - Ellison, Christopher J.

AU - Dong, Guangbin

AU - Grant Willson, C.

PY - 2016/5/24

Y1 - 2016/5/24

N2 - The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.

AB - The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.

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UR - https://www.scopus.com/pages/publications/84971264970#tab=citedBy

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JO - Macromolecules

JF - Macromolecules

IS - 10

ER -

Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers

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