Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers

Colin O. Hayes; Peng Hao Chen; R. Paxton Thedford; Christopher J. Ellison; Guangbin Dong; C. Grant Willson

doi:10.1021/acs.macromol.6b00316

Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers

Colin O. Hayes, Peng Hao Chen, R. Paxton Thedford, Christopher J. Ellison, Guangbin Dong, C. Grant Willson

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.

Original language	English (US)
Pages (from-to)	3706-3715
Number of pages	10
Journal	Macromolecules
Volume	49
Issue number	10
DOIs	https://doi.org/10.1021/acs.macromol.6b00316
State	Published - May 24 2016

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© 2016 American Chemical Society.

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abstract = "The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.",

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AU - Thedford, R. Paxton

AU - Ellison, Christopher J.

AU - Dong, Guangbin

AU - Grant Willson, C.

PY - 2016/5/24

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AB - The temperature required to induce cross-linking in typical benzocyclobutene-based thermosets is near 250 °C, which exceeds the use temperature of many chemical components. A new and versatile synthesis of BCB-functionalized monomers has allowed access to monomers that can be incorporated into a variety of macromolecular platforms to enable significantly reduced cure temperatures. Incorporation of BCB-functionalized comonomers in polystyrene and polynorbornene enabled insolublization of thin films by curing at only 120 °C for 1 h.

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Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers

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