Abstract
Applications of dynamic light scattering to the characterization of multicomponent polymer solutions are described. Examples include block copolymers in a selective solvent, which can aggregate into micellar structures; block copolymers in a neutral solvent, in which an unanticipated mode due to chain diffusion appears; probe diffusion in refractive index-matched matrix solutions. The underlying linear response theory is summarized, and the main experimental aspects are noted.
Original language | English (US) |
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Pages (from-to) | 323-334 |
Number of pages | 12 |
Journal | International Journal of Polymer Analysis and Characterization |
Volume | 2 |
Issue number | 4 |
DOIs | |
State | Published - 1996 |
Bibliographical note
Funding Information:This work was supported by the National Science Foundation through Grant DMR-9019907, and by the Center for Interfacial Engineering, an NSF-supported Engineering Research Center at the University of Minnesota. The willingness of B. Lam and Z. Liu to provide the data in Figures 1 and 2 is appreciated.
Keywords
- Block copolymers
- Dynamic light scattering
- Micelles
- Multicomponent polymer solutions
- Polymer diffusion