Dynamic light scattering from multicomponent polymer solutions

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Abstract

Applications of dynamic light scattering to the characterization of multicomponent polymer solutions are described. Examples include block copolymers in a selective solvent, which can aggregate into micellar structures; block copolymers in a neutral solvent, in which an unanticipated mode due to chain diffusion appears; probe diffusion in refractive index-matched matrix solutions. The underlying linear response theory is summarized, and the main experimental aspects are noted.

Original languageEnglish (US)
Pages (from-to)323-334
Number of pages12
JournalInternational Journal of Polymer Analysis and Characterization
Volume2
Issue number4
DOIs
StatePublished - 1996

Bibliographical note

Funding Information:
This work was supported by the National Science Foundation through Grant DMR-9019907, and by the Center for Interfacial Engineering, an NSF-supported Engineering Research Center at the University of Minnesota. The willingness of B. Lam and Z. Liu to provide the data in Figures 1 and 2 is appreciated.

Keywords

  • Block copolymers
  • Dynamic light scattering
  • Micelles
  • Multicomponent polymer solutions
  • Polymer diffusion

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