Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption

Dariusz Matoga, Barbara Gil, Wojciech Nitek, Alexander D. Todd, Christopher W. Bielawski

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

A 2D layered microporous isonicotinate-supported manganese(ii) metal-organic framework was found to exhibit a reversible crystal-to-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2versus N 2.

Original languageEnglish (US)
Pages (from-to)4959-4962
Number of pages4
JournalCrystEngComm
Volume16
Issue number23
DOIs
StatePublished - Jun 21 2014

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