Doping-addition of arylsulfenyl chlorides to the tricyclo[4,2,2,02,5]deca-3,7,9-triene system: skeletal rearrangements and serendipitious products

Nikolai S. Zefirov, A. S. Koz'min, V. V. Zhdankin, V. N. Kirin, I. V. Bodrikov, B. B. Sedov, V. G. Rau

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Abstract

"doping-addition" of 2-NO2C6H4SCl to the tricyclo[4,2,2,02,5]deca-3,7,9-triene system {A figure is presented} occurs to give unusual products: (i) rearranged caged cyclopropane {A figure is presented} and (ii) the stable cross-perchlorate {A figure is presented}.

Original languageEnglish (US)
Pages (from-to)3533-3536
Number of pages4
JournalTetrahedron Letters
Volume20
Issue number37
DOIs
StatePublished - 1979

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