Direct Azidation of Adamantane and Norbornane by Stable Azidoiodinanes

Alexei P. Krasutsky, Chris J. Kuehl, Viktor Zhdankin

Research output: Contribution to journalArticle

51 Scopus citations

Abstract

Stable azidoiodinanes 1 and 2 react with norbornane, adamantane and 1,3-dimethyladamantane upon heating in the presence of catalytic amounts benzoyl peroxide with the formation of the respective azides 6-8 in moderate yields. In these reactions, reagent 2 can be generated in situ from 2-iodosobenzoic acid and azidotrimethylsilane, and used without isolation.

Original languageEnglish (US)
Pages (from-to)1081-1082
Number of pages2
JournalSynlett
Volume1995
Issue number10
DOIs
StatePublished - Oct 1995
Externally publishedYes

Keywords

  • 1-azidoadamantane
  • 2-azidonorbornane
  • azides
  • azidoiodinane
  • iodine

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