Dimethyl ether carbonylation to methyl acetate on acidic zeolites

Aditya Bhan, Patricia Cheung, Glenn Sunley, Enrique Iglesia

Research output: Chapter in Book/Report/Conference proceedingConference contribution


Acidic zeolites catalyze dimethyl ether (DME) carbonylation to methyl acetate at 400-450 K with selectivity > 99%. Steady-state, transient, and isotopic exchange studies were combined with adsorption-desorption of probe molecules and IR spectroscopy to identify methyl and acetyl groups as adsorbed species and to propose elementary steps consistent with kinetic and spectroscopic evidence. Carbonylation rates were proportional to CO pressure up to ∼ 1 MPa and independent of DME pressure. Water strongly inhibited rates but did not influence CO and DME kinetic dependences. Carbonylation proceeded via initiation steps that form methyl groups via DME-OH reactions. Subsequent propagation steps involve slow carbonylation of methyl or oxonium ions and fast methylation of the resulting acetyls with DME to re-form methyl groups. These steps avoided the formation of water and its inhibitory effects, prevalent in similar reactions of methanol. Carbonylation rates (per Al) depended strongly on zeolite structure and on the density of acidic OH groups, but not on the number and type of inorganic cations that bind CO. This is an abstract of a paper presented at the AIChE Annual Meeting (San Francisco, CA 11/12-17/2006).

Original languageEnglish (US)
Title of host publication2006 AIChE Annual Meeting
StatePublished - Dec 1 2006
Event2006 AIChE Annual Meeting - San Francisco, CA, United States
Duration: Nov 12 2006Nov 17 2006

Publication series

NameAIChE Annual Meeting, Conference Proceedings


Other2006 AIChE Annual Meeting
Country/TerritoryUnited States
CitySan Francisco, CA


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