Diisocyanoarene-linked pentacarbonylvanadate(I-) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π-π And contact ion interactions

Tiffany R. Maher; John J. Meyers; Andrew D. Spaeth; Krista R. Lemley; Mikhail V. Barybin

doi:10.1039/c2dt30488k

Diisocyanoarene-linked pentacarbonylvanadate(I-) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π-π And contact ion interactions

Tiffany R. Maher
, John J. Meyers
, Andrew D. Spaeth
, Krista R. Lemley
, Mikhail V. Barybin

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Three synthetic routes to the unusual supramolecular complex ([Cp ₂Co] ₂[{(OC) ₅V} ₂(μ-1,4-CNC ₆Me ₄NC)]) _∞, which was crystallographically characterized, are presented. The dianion [{(OC) ₅V} ₂(μ-1,4-CNC ₆Me ₄NC)] ^2- constitutes the first subvalent organometallics featuring a diisocyanoarene linker.

Original language	English (US)
Pages (from-to)	7845-7848
Number of pages	4
Journal	Dalton Transactions
Volume	41
Issue number	26
DOIs	https://doi.org/10.1039/c2dt30488k
State	Published - Jul 14 2012
Externally published	Yes

Publisher link

10.1039/c2dt30488k

Find It

Find It at U of M Libraries

Cite this

Diisocyanoarene-linked pentacarbonylvanadate(I-) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π-π And contact ion interactions. / Maher, Tiffany R.; Meyers, John J.; Spaeth, Andrew D. et al.
In: Dalton Transactions, Vol. 41, No. 26, 14.07.2012, p. 7845-7848.

Research output: Contribution to journal › Article › peer-review

@article{5161467c9bc0499a930e5ed67911910e,

title = "Diisocyanoarene-linked pentacarbonylvanadate(I-) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π-π And contact ion interactions",

abstract = "Three synthetic routes to the unusual supramolecular complex ([Cp 2Co] 2[\{(OC) 5V\} 2(μ-1,4-CNC 6Me 4NC)]) ∞, which was crystallographically characterized, are presented. The dianion [\{(OC) 5V\} 2(μ-1,4-CNC 6Me 4NC)] 2- constitutes the first subvalent organometallics featuring a diisocyanoarene linker.",

author = "Maher, \{Tiffany R.\} and Meyers, \{John J.\} and Spaeth, \{Andrew D.\} and Lemley, \{Krista R.\} and Barybin, \{Mikhail V.\}",

year = "2012",

month = jul,

day = "14",

doi = "10.1039/c2dt30488k",

language = "English (US)",

volume = "41",

pages = "7845--7848",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "26",

}

TY - JOUR

T1 - Diisocyanoarene-linked pentacarbonylvanadate(I-) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π-π And contact ion interactions

AU - Maher, Tiffany R.

AU - Meyers, John J.

AU - Spaeth, Andrew D.

AU - Lemley, Krista R.

AU - Barybin, Mikhail V.

PY - 2012/7/14

Y1 - 2012/7/14

N2 - Three synthetic routes to the unusual supramolecular complex ([Cp 2Co] 2[{(OC) 5V} 2(μ-1,4-CNC 6Me 4NC)]) ∞, which was crystallographically characterized, are presented. The dianion [{(OC) 5V} 2(μ-1,4-CNC 6Me 4NC)] 2- constitutes the first subvalent organometallics featuring a diisocyanoarene linker.

AB - Three synthetic routes to the unusual supramolecular complex ([Cp 2Co] 2[{(OC) 5V} 2(μ-1,4-CNC 6Me 4NC)]) ∞, which was crystallographically characterized, are presented. The dianion [{(OC) 5V} 2(μ-1,4-CNC 6Me 4NC)] 2- constitutes the first subvalent organometallics featuring a diisocyanoarene linker.

UR - https://www.scopus.com/pages/publications/84862531054

UR - https://www.scopus.com/pages/publications/84862531054#tab=citedBy

U2 - 10.1039/c2dt30488k

DO - 10.1039/c2dt30488k

M3 - Article

C2 - 22508293

AN - SCOPUS:84862531054

SN - 1477-9226

VL - 41

SP - 7845

EP - 7848

JO - Dalton Transactions

JF - Dalton Transactions

IS - 26

ER -

Diisocyanoarene-linked pentacarbonylvanadate(I-) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π-π And contact ion interactions

Abstract

Publisher link

Find It

Other files and links

Fingerprint

Cite this