Diisocyanoarene-linked pentacarbonylvanadate(I-) ions as building blocks in a supramolecular charge-transfer framework assembled through noncovalent π-π And contact ion interactions

Tiffany R. Maher, John J. Meyers, Andrew D. Spaeth, Krista R. Lemley, Mikhail V. Barybin

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Three synthetic routes to the unusual supramolecular complex ([Cp 2Co] 2[{(OC) 5V} 2(μ-1,4-CNC 6Me 4NC)]) , which was crystallographically characterized, are presented. The dianion [{(OC) 5V} 2(μ-1,4-CNC 6Me 4NC)] 2- constitutes the first subvalent organometallics featuring a diisocyanoarene linker.

Original languageEnglish (US)
Pages (from-to)7845-7848
Number of pages4
JournalDalton Transactions
Volume41
Issue number26
DOIs
StatePublished - Jul 14 2012

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