Digital Impedance for Faradaic Analysis III. Copper Corrosion in Oxygenated 0.1N HCl

William H. Smyrl; Larry L. Stephenson

doi:10.1149/1.2114165

Digital Impedance for Faradaic Analysis III. Copper Corrosion in Oxygenated 0.1N HCl

William H. Smyrl, Larry L. Stephenson

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Impedance measurements have been made on copper rotating disks corroding in oxygenated 0.1N HCI. A model is developed here for the first time for the faradaic impedance of a corrosion couple consisting of an anodic dissolution reaction dominated by convective diffusion and a cathodic reaction under kinetic control. The model was found to be obeyed for all values of disk rotation rate, oxygen concentration, and voltage excitation frequency. The corrosion rate was found to depend on oxygen concentration to the 2/3 power, and on rotation rate to the 1/6 power.

Original language	English (US)
Pages (from-to)	1563-1567
Number of pages	5
Journal	Journal of the Electrochemical Society
Volume	132
Issue number	7
DOIs	https://doi.org/10.1149/1.2114165
State	Published - Jul 1985

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Publisher link

10.1149/1.2114165

Find It

Find It at U of M Libraries

Cite this

@article{058b9a2c9f714a02942b8a271ef2a5ee,

title = "Digital Impedance for Faradaic Analysis III. Copper Corrosion in Oxygenated 0.1N HCl",

abstract = "Impedance measurements have been made on copper rotating disks corroding in oxygenated 0.1N HCI. A model is developed here for the first time for the faradaic impedance of a corrosion couple consisting of an anodic dissolution reaction dominated by convective diffusion and a cathodic reaction under kinetic control. The model was found to be obeyed for all values of disk rotation rate, oxygen concentration, and voltage excitation frequency. The corrosion rate was found to depend on oxygen concentration to the 2/3 power, and on rotation rate to the 1/6 power.",

author = "Smyrl, {William H.} and Stephenson, {Larry L.}",

year = "1985",

month = jul,

doi = "10.1149/1.2114165",

language = "English (US)",

volume = "132",

pages = "1563--1567",

journal = "Journal of the Electrochemical Society",

issn = "0013-4651",

publisher = "Electrochemical Society, Inc.",

number = "7",

}

TY - JOUR

T1 - Digital Impedance for Faradaic Analysis III. Copper Corrosion in Oxygenated 0.1N HCl

AU - Smyrl, William H.

AU - Stephenson, Larry L.

PY - 1985/7

Y1 - 1985/7

N2 - Impedance measurements have been made on copper rotating disks corroding in oxygenated 0.1N HCI. A model is developed here for the first time for the faradaic impedance of a corrosion couple consisting of an anodic dissolution reaction dominated by convective diffusion and a cathodic reaction under kinetic control. The model was found to be obeyed for all values of disk rotation rate, oxygen concentration, and voltage excitation frequency. The corrosion rate was found to depend on oxygen concentration to the 2/3 power, and on rotation rate to the 1/6 power.

AB - Impedance measurements have been made on copper rotating disks corroding in oxygenated 0.1N HCI. A model is developed here for the first time for the faradaic impedance of a corrosion couple consisting of an anodic dissolution reaction dominated by convective diffusion and a cathodic reaction under kinetic control. The model was found to be obeyed for all values of disk rotation rate, oxygen concentration, and voltage excitation frequency. The corrosion rate was found to depend on oxygen concentration to the 2/3 power, and on rotation rate to the 1/6 power.

UR - http://www.scopus.com/inward/record.url?scp=0022092601&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022092601&partnerID=8YFLogxK

U2 - 10.1149/1.2114165

DO - 10.1149/1.2114165

M3 - Article

AN - SCOPUS:0022092601

SN - 0013-4651

VL - 132

SP - 1563

EP - 1567

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

IS - 7

ER -

Digital Impedance for Faradaic Analysis III. Copper Corrosion in Oxygenated 0.1N HCl

Abstract

UN SDGs

Publisher link

Find It

Other files and links

Fingerprint

Cite this