Difluorocarbene addition to model polydienes: a new class of fluoropolymers

Yu Ren, Stephen J. Engel, Timothy P. Lodge, Marc A. Hillmyer

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The addition of difluorocarbene (:CF2) to unsaturated sites in polyisoprene (PI) a model homopolymer substrate was investigated. Three routes were investigated for the :CF2 modification of a narrow-molecular-weight distribution. Initial experiments using the three system led to partial fluorination of the model PI, but the products were partially crosslinked and the molecular weight distribution of the fluorinated material was not narrow.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Editors Anon
PublisherACS
Pages823
Number of pages1
Volume39
Edition2
StatePublished - Aug 1998
EventProceedings of the 1997 Boston Meeting - Boston, MA, USA
Duration: Aug 23 1998Aug 27 1998

Other

OtherProceedings of the 1997 Boston Meeting
CityBoston, MA, USA
Period8/23/988/27/98

Fingerprint

Fluorine containing polymers
Polyisoprenes
Molecular weight distribution
Fluorination
Homopolymerization
Substrates
Experiments
difluorocarbene

Cite this

Ren, Y., Engel, S. J., Lodge, T. P., & Hillmyer, M. A. (1998). Difluorocarbene addition to model polydienes: a new class of fluoropolymers. In Anon (Ed.), American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 39, pp. 823). ACS.

Difluorocarbene addition to model polydienes : a new class of fluoropolymers. / Ren, Yu; Engel, Stephen J.; Lodge, Timothy P.; Hillmyer, Marc A.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. ed. / Anon. Vol. 39 2. ed. ACS, 1998. p. 823.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Ren, Y, Engel, SJ, Lodge, TP & Hillmyer, MA 1998, Difluorocarbene addition to model polydienes: a new class of fluoropolymers. in Anon (ed.), American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 edn, vol. 39, ACS, pp. 823, Proceedings of the 1997 Boston Meeting, Boston, MA, USA, 8/23/98.
Ren Y, Engel SJ, Lodge TP, Hillmyer MA. Difluorocarbene addition to model polydienes: a new class of fluoropolymers. In Anon, editor, American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 ed. Vol. 39. ACS. 1998. p. 823
Ren, Yu ; Engel, Stephen J. ; Lodge, Timothy P. ; Hillmyer, Marc A. / Difluorocarbene addition to model polydienes : a new class of fluoropolymers. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. editor / Anon. Vol. 39 2. ed. ACS, 1998. pp. 823
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