Aiming at the enhancement of electrophilicity of imino-λ3-iodanes, we have developed (tosylimino)pentafluorophenyl-λ3-iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl-λ3-iodane in the [2+2+1]-type synthesis of imidazoles. (Figure presented.).
|Original language||English (US)|
|Number of pages||5|
|Journal||Advanced Synthesis and Catalysis|
|State||Published - Nov 10 2017|
Bibliographical noteFunding Information:
This work was partially supported by JSPS Grants-in-Aid for Scientific Research (C) (Grant No 15 K07852), by the Asahi Glass Foundation and by the Takeda Science Foundation. V.V.Z. is also thankful to the National Science Foundation (CHE-1262479).
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim