Deuterium Kinetic Isotope Effects and their Temperature Dependence in the Gas-Phase S_N2 Reactions X^–+ CH₃Y → CH₃X + Y^–(X, Y = Cl, Br, I)

Keyphrases

• Gas Phase 100%
• Temperature Effect 100%
• Kinetic Isotope Effect 100%
• Deuterium Isotope Effect 100%
• SN2 Reaction 100%
• Methyl Iodide 66%
• CH3Br 66%
• Chloromethane 66%
• Statistical Theory 33%
• Force Field 33%
• Transition State 33%
• Conventional Transition State Theory 33%
• Theory Calculation 33%
• Extended Basis 33%
• Electron Correlation 33%
• Transition State Theory 33%
• State Property 33%

Chemistry

• Kinetic Isotope Effect 100%
• Transition State Theory 50%
• Transition State 25%
• Rate Constant 25%
• Electron Correlation 25%