Determination of Aqueous Chlorination Reaction Products of Polynuclear Aromatic Hydrocarbons by Reversed Phase High Performance Liquid Chromatography-Gas Chromatography

Alan R Oyler; D. L. Bodenner; K. J. Welch; R. J. Liukkonen; Robert M Carlson; H. L. Kopperman; R. Caple

doi:10.1021/ac50029a005

Determination of Aqueous Chlorination Reaction Products of Polynuclear Aromatic Hydrocarbons by Reversed Phase High Performance Liquid Chromatography-Gas Chromatography

Alan R Oyler, D. L. Bodenner, K. J. Welch, R. J. Liukkonen, Robert M Carlson, H. L. Kopperman, R. Caple

Chemistry & Biochemistry

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Abstract

A convenient procedure is described for the quantitation of polynuclear aromatic hydrocarbons (PAH) in water at the nanogram to microgram per liter level. The procedure involves forcing an aqueous sample through a glass microfiber filter connected In series with a 7 × 50 mm C-18 high performance liquid chromatography (HPLC) column. The HPLC column containing the PAH material Is then attached to a C-18 micropacked reverse-phase setup and eluted with an acetonitrile-water gradient. Fractions corresponding to each UV peak are collected and these aqueous-acetonitrile fractions are then Injected directly into a gas chromatograph (GC) equipped with a photolonizatlon detector (PID). Application of this procedure to the study of aqueous chlorination reactions of several polynuclear aromatic hydrocarbons is described. Anthraquinone, a chlorohydrin of fluoranthene, and a monochloro derivative of fluorene, phenanthrene, 1-methylphenanthrene, and 1-methyinaphthalene were identified and quantltated.

Original language	English (US)
Pages (from-to)	837-842
Number of pages	6
Journal	Analytical chemistry
Volume	50
Issue number	7
DOIs	https://doi.org/10.1021/ac50029a005
State	Published - 1978

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title = "Determination of Aqueous Chlorination Reaction Products of Polynuclear Aromatic Hydrocarbons by Reversed Phase High Performance Liquid Chromatography-Gas Chromatography",

abstract = "A convenient procedure is described for the quantitation of polynuclear aromatic hydrocarbons (PAH) in water at the nanogram to microgram per liter level. The procedure involves forcing an aqueous sample through a glass microfiber filter connected In series with a 7 × 50 mm C-18 high performance liquid chromatography (HPLC) column. The HPLC column containing the PAH material Is then attached to a C-18 micropacked reverse-phase setup and eluted with an acetonitrile-water gradient. Fractions corresponding to each UV peak are collected and these aqueous-acetonitrile fractions are then Injected directly into a gas chromatograph (GC) equipped with a photolonizatlon detector (PID). Application of this procedure to the study of aqueous chlorination reactions of several polynuclear aromatic hydrocarbons is described. Anthraquinone, a chlorohydrin of fluoranthene, and a monochloro derivative of fluorene, phenanthrene, 1-methylphenanthrene, and 1-methyinaphthalene were identified and quantltated.",

author = "Oyler, {Alan R} and Bodenner, {D. L.} and Welch, {K. J.} and Liukkonen, {R. J.} and Carlson, {Robert M} and Kopperman, {H. L.} and R. Caple",

year = "1978",

doi = "10.1021/ac50029a005",

language = "English (US)",

volume = "50",

pages = "837--842",

journal = "Industrial And Engineering Chemistry Analytical Edition",

issn = "0003-2700",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Determination of Aqueous Chlorination Reaction Products of Polynuclear Aromatic Hydrocarbons by Reversed Phase High Performance Liquid Chromatography-Gas Chromatography

AU - Oyler, Alan R

AU - Bodenner, D. L.

AU - Welch, K. J.

AU - Liukkonen, R. J.

AU - Carlson, Robert M

AU - Kopperman, H. L.

AU - Caple, R.

PY - 1978

Y1 - 1978

N2 - A convenient procedure is described for the quantitation of polynuclear aromatic hydrocarbons (PAH) in water at the nanogram to microgram per liter level. The procedure involves forcing an aqueous sample through a glass microfiber filter connected In series with a 7 × 50 mm C-18 high performance liquid chromatography (HPLC) column. The HPLC column containing the PAH material Is then attached to a C-18 micropacked reverse-phase setup and eluted with an acetonitrile-water gradient. Fractions corresponding to each UV peak are collected and these aqueous-acetonitrile fractions are then Injected directly into a gas chromatograph (GC) equipped with a photolonizatlon detector (PID). Application of this procedure to the study of aqueous chlorination reactions of several polynuclear aromatic hydrocarbons is described. Anthraquinone, a chlorohydrin of fluoranthene, and a monochloro derivative of fluorene, phenanthrene, 1-methylphenanthrene, and 1-methyinaphthalene were identified and quantltated.

AB - A convenient procedure is described for the quantitation of polynuclear aromatic hydrocarbons (PAH) in water at the nanogram to microgram per liter level. The procedure involves forcing an aqueous sample through a glass microfiber filter connected In series with a 7 × 50 mm C-18 high performance liquid chromatography (HPLC) column. The HPLC column containing the PAH material Is then attached to a C-18 micropacked reverse-phase setup and eluted with an acetonitrile-water gradient. Fractions corresponding to each UV peak are collected and these aqueous-acetonitrile fractions are then Injected directly into a gas chromatograph (GC) equipped with a photolonizatlon detector (PID). Application of this procedure to the study of aqueous chlorination reactions of several polynuclear aromatic hydrocarbons is described. Anthraquinone, a chlorohydrin of fluoranthene, and a monochloro derivative of fluorene, phenanthrene, 1-methylphenanthrene, and 1-methyinaphthalene were identified and quantltated.

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DO - 10.1021/ac50029a005

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SN - 0003-2700

VL - 50

SP - 837

EP - 842

JO - Industrial And Engineering Chemistry Analytical Edition

JF - Industrial And Engineering Chemistry Analytical Edition

IS - 7

ER -

Determination of Aqueous Chlorination Reaction Products of Polynuclear Aromatic Hydrocarbons by Reversed Phase High Performance Liquid Chromatography-Gas Chromatography

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