Detection of a transient FeV(O)(OH) species involved in olefin oxidation by a bio-inspired non-haem iron catalyst

Shuangning Xu, Jedidiah J. Veach, Williamson N. Oloo, Kevin C. Peters, Junyi Wang, Richard H. Perry, Lawrence Que

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The Fe(TPA) (TPA = tris(pyridyl-2-methyl)amine) class of non-haem Fe catalysts is proposed to carry out selective hydrocarbon oxidations through the generation of high-valent iron species. Using ambient mass spectrometry, we obtain direct evidence for the formation of an FeV(O)(OH) species under catalytic conditions. In addition, 18O-labelling suggests that this FeV(O)(OH) species serves as the active oxidant in hydrocarbon oxidation catalysis.

Original languageEnglish (US)
Pages (from-to)8701-8704
Number of pages4
JournalChemical Communications
Volume54
Issue number63
DOIs
StatePublished - Jan 1 2018

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Alkenes
Hydrocarbons
Olefins
Iron
Oxidation
Catalysts
Oxidants
Labeling
Catalysis
Amines
Mass spectrometry

Cite this

Detection of a transient FeV(O)(OH) species involved in olefin oxidation by a bio-inspired non-haem iron catalyst. / Xu, Shuangning; Veach, Jedidiah J.; Oloo, Williamson N.; Peters, Kevin C.; Wang, Junyi; Perry, Richard H.; Que, Lawrence.

In: Chemical Communications, Vol. 54, No. 63, 01.01.2018, p. 8701-8704.

Research output: Contribution to journalArticle

Xu, Shuangning ; Veach, Jedidiah J. ; Oloo, Williamson N. ; Peters, Kevin C. ; Wang, Junyi ; Perry, Richard H. ; Que, Lawrence. / Detection of a transient FeV(O)(OH) species involved in olefin oxidation by a bio-inspired non-haem iron catalyst. In: Chemical Communications. 2018 ; Vol. 54, No. 63. pp. 8701-8704.
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