Desulfinylation of Ag(I) Sulfinyl Mesoionic Carbenes: Preparation of C-Unsubstituted Au(I)-1,2,3-Triazole Carbene Complexes

Keyphrases

• Carbene Complexes 100%
• I(1) 100%
• 1,2,3-triazole 100%
• Au(I) Complex 100%
• Ag(I) 100%
• Sulfinyl Chloride 100%
• Sulfinylation 100%
• Mesoionic Carbenes 100%
• 1,2,3-triazolylidene 66%
• Alcohol 33%
• Sequential Treatment 33%
• DFT Calculations 33%
• Sulfoxide 33%
• Bis-1 33%
• Regioisomers 33%
• In Situ Generated 33%
• Triazolylidenes 33%
• Mechanistic Studies 33%
• Enantiopure 33%

Chemistry

• 1,2,3-triazole 100%
• Carbene 100%
• Mechanistic Study 50%
• Enantiopurity 50%
• Sulfoxide 50%
• Density Functional Theory 50%