Design of molecules with large two-photon absorptivities

M. Rumi; J. E. Ehrlich; A. A. Heikal; J. Fu; S. Barlow; M. D. Levin; L. Erskine; D. McCord-Maughon; H. Rockel; G. Subramanian; S. Thayumanavan; J. W. Perry; S. R. Marder; T. Kogej; D. Beljonne

Design of molecules with large two-photon absorptivities

M. Rumi
, J. E. Ehrlich
, A. A. Heikal
, J. Fu
, S. Barlow
, M. D. Levin
, L. Erskine
, D. McCord-Maughon
, H. Rockel
, G. Subramanian
, S. Thayumanavan
, J. W. Perry
, S. R. Marder
, T. Kogej
, D. Beljonne

Chemistry & Biochemistry

Research output: Contribution to conference › Paper › peer-review

Abstract

The guidelines for the design of both centrosymmetric and bipolar chromophores with large two-photon absorptivities are developed, based upon theoretical, synthetic, and nonlinear spectroscopic studies. Theoretical studies were performed on a donor-acceptor stilbene in which the ground-state polarization is varied by application of an electric field. An optimal value of ground-state polarization is present at which δ for the lowest lying strong two-photon transition was optimized. This condition was met when the molecule had roughly the correct degree of ground-state polarization required to maximize the first hyperpolarizability.

Original language	English (US)
Pages	37-38
Number of pages	2
State	Published - 1998
Event	Proceedings of the 1998 International Quantum Electronics Conference - San Francisco, CA, USA Duration: May 3 1998 → May 8 1998

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Other	Proceedings of the 1998 International Quantum Electronics Conference
City	San Francisco, CA, USA
Period	5/3/98 → 5/8/98

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Rumi, M., Ehrlich, J. E., Heikal, A. A., Fu, J., Barlow, S., Levin, M. D., Erskine, L., McCord-Maughon, D., Rockel, H., Subramanian, G., Thayumanavan, S., Perry, J. W., Marder, S. R., Kogej, T., & Beljonne, D. (1998). Design of molecules with large two-photon absorptivities. 37-38. Paper presented at Proceedings of the 1998 International Quantum Electronics Conference, San Francisco, CA, USA.

Rumi, M, Ehrlich, JE, Heikal, AA, Fu, J, Barlow, S, Levin, MD, Erskine, L, McCord-Maughon, D, Rockel, H, Subramanian, G, Thayumanavan, S, Perry, JW, Marder, SR, Kogej, T & Beljonne, D 1998, 'Design of molecules with large two-photon absorptivities', Paper presented at Proceedings of the 1998 International Quantum Electronics Conference, San Francisco, CA, USA, 5/3/98 - 5/8/98 pp. 37-38.

@conference{77d6190361514e5190a7f72a72035ad5,

title = "Design of molecules with large two-photon absorptivities",

abstract = "The guidelines for the design of both centrosymmetric and bipolar chromophores with large two-photon absorptivities are developed, based upon theoretical, synthetic, and nonlinear spectroscopic studies. Theoretical studies were performed on a donor-acceptor stilbene in which the ground-state polarization is varied by application of an electric field. An optimal value of ground-state polarization is present at which δ for the lowest lying strong two-photon transition was optimized. This condition was met when the molecule had roughly the correct degree of ground-state polarization required to maximize the first hyperpolarizability.",

author = "M. Rumi and Ehrlich, \{J. E.\} and Heikal, \{A. A.\} and J. Fu and S. Barlow and Levin, \{M. D.\} and L. Erskine and D. McCord-Maughon and H. Rockel and G. Subramanian and S. Thayumanavan and Perry, \{J. W.\} and Marder, \{S. R.\} and T. Kogej and D. Beljonne",

year = "1998",

language = "English (US)",

pages = "37--38",

note = "Proceedings of the 1998 International Quantum Electronics Conference ; Conference date: 03-05-1998 Through 08-05-1998",

}

TY - CONF

T1 - Design of molecules with large two-photon absorptivities

AU - Rumi, M.

AU - Ehrlich, J. E.

AU - Heikal, A. A.

AU - Fu, J.

AU - Barlow, S.

AU - Levin, M. D.

AU - Erskine, L.

AU - McCord-Maughon, D.

AU - Rockel, H.

AU - Subramanian, G.

AU - Thayumanavan, S.

AU - Perry, J. W.

AU - Marder, S. R.

AU - Kogej, T.

AU - Beljonne, D.

PY - 1998

Y1 - 1998

N2 - The guidelines for the design of both centrosymmetric and bipolar chromophores with large two-photon absorptivities are developed, based upon theoretical, synthetic, and nonlinear spectroscopic studies. Theoretical studies were performed on a donor-acceptor stilbene in which the ground-state polarization is varied by application of an electric field. An optimal value of ground-state polarization is present at which δ for the lowest lying strong two-photon transition was optimized. This condition was met when the molecule had roughly the correct degree of ground-state polarization required to maximize the first hyperpolarizability.

AB - The guidelines for the design of both centrosymmetric and bipolar chromophores with large two-photon absorptivities are developed, based upon theoretical, synthetic, and nonlinear spectroscopic studies. Theoretical studies were performed on a donor-acceptor stilbene in which the ground-state polarization is varied by application of an electric field. An optimal value of ground-state polarization is present at which δ for the lowest lying strong two-photon transition was optimized. This condition was met when the molecule had roughly the correct degree of ground-state polarization required to maximize the first hyperpolarizability.

UR - https://www.scopus.com/pages/publications/0031651174

UR - https://www.scopus.com/pages/publications/0031651174#tab=citedBy

M3 - Paper

AN - SCOPUS:0031651174

SP - 37

EP - 38

T2 - Proceedings of the 1998 International Quantum Electronics Conference

Y2 - 3 May 1998 through 8 May 1998

ER -

Design of molecules with large two-photon absorptivities

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