Derivatives of tricarbonylmetallates(-III) of cobalt, rhodium, and iridium

John E. Ellis; Paul T. Barger; Mark L. Winzenburg

doi:10.1039/C39770000686

Derivatives of tricarbonylmetallates(-III) of cobalt, rhodium, and iridium

John E. Ellis, Paul T. Barger, Mark L. Winzenburg

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Reduction of [Co(CO)₄]^- or [M(CO)₃] ₄ (M = Rh and Ir) with sodium in liquid ammonia, naphthalene- tetrahydrofuran, or hexamethylphosphoramide (only M = Rh and Ir) gives pyrophoric substances which provide the first main group 4 derivatives of [M(CO)₃]^3- (M = Co, Rh, and Ir) in 20-90% yields.

Original language	English (US)
Pages (from-to)	686-687
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39770000686
State	Published - Dec 1 1977

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title = "Derivatives of tricarbonylmetallates(-III) of cobalt, rhodium, and iridium",

abstract = "Reduction of [Co(CO)4]- or [M(CO)3] 4 (M = Rh and Ir) with sodium in liquid ammonia, naphthalene- tetrahydrofuran, or hexamethylphosphoramide (only M = Rh and Ir) gives pyrophoric substances which provide the first main group 4 derivatives of [M(CO)3]3- (M = Co, Rh, and Ir) in 20-90% yields.",

author = "Ellis, {John E.} and Barger, {Paul T.} and Winzenburg, {Mark L.}",

year = "1977",

month = dec,

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doi = "10.1039/C39770000686",

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T1 - Derivatives of tricarbonylmetallates(-III) of cobalt, rhodium, and iridium

AU - Ellis, John E.

AU - Barger, Paul T.

AU - Winzenburg, Mark L.

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N2 - Reduction of [Co(CO)4]- or [M(CO)3] 4 (M = Rh and Ir) with sodium in liquid ammonia, naphthalene- tetrahydrofuran, or hexamethylphosphoramide (only M = Rh and Ir) gives pyrophoric substances which provide the first main group 4 derivatives of [M(CO)3]3- (M = Co, Rh, and Ir) in 20-90% yields.

AB - Reduction of [Co(CO)4]- or [M(CO)3] 4 (M = Rh and Ir) with sodium in liquid ammonia, naphthalene- tetrahydrofuran, or hexamethylphosphoramide (only M = Rh and Ir) gives pyrophoric substances which provide the first main group 4 derivatives of [M(CO)3]3- (M = Co, Rh, and Ir) in 20-90% yields.

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