Derivatives of tricarbonylmetallates(-III) of cobalt, rhodium, and iridium

John E. Ellis, Paul T. Barger, Mark L. Winzenburg

Research output: Contribution to journalArticlepeer-review

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Abstract

Reduction of [Co(CO)4]- or [M(CO)3] 4 (M = Rh and Ir) with sodium in liquid ammonia, naphthalene- tetrahydrofuran, or hexamethylphosphoramide (only M = Rh and Ir) gives pyrophoric substances which provide the first main group 4 derivatives of [M(CO)3]3- (M = Co, Rh, and Ir) in 20-90% yields.

Original languageEnglish (US)
Pages (from-to)686-687
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number19
DOIs
StatePublished - Dec 1 1977

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