Abstract
Reduction of [Co(CO)4]- or [M(CO)3] 4 (M = Rh and Ir) with sodium in liquid ammonia, naphthalene- tetrahydrofuran, or hexamethylphosphoramide (only M = Rh and Ir) gives pyrophoric substances which provide the first main group 4 derivatives of [M(CO)3]3- (M = Co, Rh, and Ir) in 20-90% yields.
Original language | English (US) |
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Pages (from-to) | 686-687 |
Number of pages | 2 |
Journal | Journal of the Chemical Society, Chemical Communications |
Issue number | 19 |
DOIs | |
State | Published - Dec 1 1977 |