Derivatives of 2-iodoxybenzenesulfonic acid: New pseudocyclic hypervalent iodine reagents

Viktor Zhdankin, Rostyslav N. Goncharenko, Dmitry N. Litvinov, Alexey Y. Koposov

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

Amides and esters of 2-iodoxybenzenesulfonic acid were prepared by dimethyldioxirane oxidation of the respective monovalent iodine derivatives and isolated as stable, microcrystalline compounds. These new hypervalent iodine reagents with a pseudobenziodoxole structure are efficient oxidizers of alcohols, secondary amines and sulfides.

Original languageEnglish (US)
Pages (from-to)8-18
Number of pages11
JournalArkivoc
Volume2005
Issue number4
StatePublished - Sep 14 2004

Keywords

  • Hypervalent iodine
  • IBX
  • Oxidation
  • Pseudobenziodoxole

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