Dechlorination of chlorinated ethylenes using a phosphinorhodium catalyst

Alicia A. Peterson; Kristopher McNeill

Dechlorination of chlorinated ethylenes using a phosphinorhodium catalyst

Alicia A. Peterson, Kristopher McNeill

Chemistry (Twin Cities)

Research output: Contribution to journal › Conference article › peer-review

Abstract

The catalytic dechlorination of chlorinated ethylenes by chlorotris(triphenylphosphine) rhodium was described. Reaction kinetics was conducted using ¹H and ³¹P NMR spectroscopy under ambient conditions. Evidence for sequential chlorine removal was obtained, such that trichloroethylene yields cis-dichloroethylene yields vinyl chloride yields ethylene. The ethylene product was subsequently dimerized to butene. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

Original language	English (US)
Journal	ACS National Meeting Book of Abstracts
Volume	230
State	Published - Dec 1 2005
Event	230th ACS National Meeting - Washington, DC, United States Duration: Aug 28 2005 → Sep 1 2005

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title = "Dechlorination of chlorinated ethylenes using a phosphinorhodium catalyst",

abstract = "The catalytic dechlorination of chlorinated ethylenes by chlorotris(triphenylphosphine) rhodium was described. Reaction kinetics was conducted using 1H and 31P NMR spectroscopy under ambient conditions. Evidence for sequential chlorine removal was obtained, such that trichloroethylene yields cis-dichloroethylene yields vinyl chloride yields ethylene. The ethylene product was subsequently dimerized to butene. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).",

author = "Peterson, {Alicia A.} and Kristopher McNeill",

year = "2005",

month = dec,

day = "1",

language = "English (US)",

volume = "230",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

note = "230th ACS National Meeting ; Conference date: 28-08-2005 Through 01-09-2005",

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TY - JOUR

T1 - Dechlorination of chlorinated ethylenes using a phosphinorhodium catalyst

AU - Peterson, Alicia A.

AU - McNeill, Kristopher

PY - 2005/12/1

Y1 - 2005/12/1

N2 - The catalytic dechlorination of chlorinated ethylenes by chlorotris(triphenylphosphine) rhodium was described. Reaction kinetics was conducted using 1H and 31P NMR spectroscopy under ambient conditions. Evidence for sequential chlorine removal was obtained, such that trichloroethylene yields cis-dichloroethylene yields vinyl chloride yields ethylene. The ethylene product was subsequently dimerized to butene. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

AB - The catalytic dechlorination of chlorinated ethylenes by chlorotris(triphenylphosphine) rhodium was described. Reaction kinetics was conducted using 1H and 31P NMR spectroscopy under ambient conditions. Evidence for sequential chlorine removal was obtained, such that trichloroethylene yields cis-dichloroethylene yields vinyl chloride yields ethylene. The ethylene product was subsequently dimerized to butene. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

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M3 - Conference article

AN - SCOPUS:33745393904

SN - 0065-7727

VL - 230

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

T2 - 230th ACS National Meeting

Y2 - 28 August 2005 through 1 September 2005

ER -

Dechlorination of chlorinated ethylenes using a phosphinorhodium catalyst

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