Deacylative allylation of nitroalkanes: Unsymmetric bisallylation by a three-component coupling

Alexander J. Grenning, Jon A. Tunge

Research output: Contribution to journalArticlepeer-review

50 Scopus citations

Abstract

Use it and lose it! Allylic alcohols were used directly for the synthesis of diallylated nitroalkanes in a three-component coupling based on the strategy of deacylative allylation for the in situ generation of a nucleophile and an allyl electrophile (see scheme).

Original languageEnglish (US)
Pages (from-to)1688-1691
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number7
DOIs
StatePublished - Feb 11 2011
Externally publishedYes

Keywords

  • 1-6-dienes
  • allylation
  • deacylation
  • multicomponent reactions
  • nitroalkanes

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