Deacylative allylation of nitroalkanes: Unsymmetric bisallylation by a three-component coupling

Alexander J. Grenning; Jon A. Tunge

doi:10.1002/anie.201006273

Deacylative allylation of nitroalkanes: Unsymmetric bisallylation by a three-component coupling

Alexander J. Grenning, Jon A. Tunge

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Use it and lose it! Allylic alcohols were used directly for the synthesis of diallylated nitroalkanes in a three-component coupling based on the strategy of deacylative allylation for the in situ generation of a nucleophile and an allyl electrophile (see scheme).

Original language	English (US)
Pages (from-to)	1688-1691
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	7
DOIs	https://doi.org/10.1002/anie.201006273
State	Published - Feb 11 2011
Externally published	Yes

Keywords

1-6-dienes
allylation
deacylation
multicomponent reactions
nitroalkanes

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10.1002/anie.201006273

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title = "Deacylative allylation of nitroalkanes: Unsymmetric bisallylation by a three-component coupling",

abstract = "Use it and lose it! Allylic alcohols were used directly for the synthesis of diallylated nitroalkanes in a three-component coupling based on the strategy of deacylative allylation for the in situ generation of a nucleophile and an allyl electrophile (see scheme).",

keywords = "1-6-dienes, allylation, deacylation, multicomponent reactions, nitroalkanes",

author = "Grenning, {Alexander J.} and Tunge, {Jon A.}",

year = "2011",

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day = "11",

doi = "10.1002/anie.201006273",

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journal = "Angewandte Chemie - International Edition",

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T1 - Deacylative allylation of nitroalkanes

T2 - Unsymmetric bisallylation by a three-component coupling

AU - Grenning, Alexander J.

AU - Tunge, Jon A.

PY - 2011/2/11

Y1 - 2011/2/11

N2 - Use it and lose it! Allylic alcohols were used directly for the synthesis of diallylated nitroalkanes in a three-component coupling based on the strategy of deacylative allylation for the in situ generation of a nucleophile and an allyl electrophile (see scheme).

AB - Use it and lose it! Allylic alcohols were used directly for the synthesis of diallylated nitroalkanes in a three-component coupling based on the strategy of deacylative allylation for the in situ generation of a nucleophile and an allyl electrophile (see scheme).

KW - 1-6-dienes

KW - allylation

KW - deacylation

KW - multicomponent reactions

KW - nitroalkanes

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M3 - Article

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AN - SCOPUS:79851496679

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ER -

Deacylative allylation of nitroalkanes: Unsymmetric bisallylation by a three-component coupling

Abstract

Keywords

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