Cycloaddition reactions of azide, furan, and pyrrole units with benzynes generated by the hexadehydro-diels-alder (HDDA) reaction

Junhua Chen, Beeraiah Baire, Thomas R. Hoye

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

Benzynes can be generated by the intramolecular thermal cycloisomerization of triynes-the title HDDA reaction. We report here that these can be trapped by cycloaddition reaction with trimethylsilyl azide (1,3-dipolar) or a furan or pyrrole (4+2 Diels-Alder).

Original languageEnglish (US)
Pages (from-to)1191-1200
Number of pages10
JournalHeterocycles
Volume88
Issue number2
DOIs
StatePublished - 2014

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