Cyanated isoindigos for n-type and ambipolar organic thin film transistors

Wan Yue; Tao He; Matthias Stolte; Marcel Gsänger; Frank Würthner

doi:10.1039/c3cc48037b

Cyanated isoindigos for n-type and ambipolar organic thin film transistors

Wan Yue, Tao He, Matthias Stolte, Marcel Gsänger, Frank Würthner

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

A set of three core-cyanated isoindigos was synthesized by palladium-catalyzed cyanation of core-brominated isoindigos. With decreased LUMO level to −3.88 eV, the dicyanated isoindigo 5 showed ambient-stable electron mobility up to 0.044 cm² V⁻¹ s⁻¹ in OTFTs with SAMs of TPA, while it exhibited ambipolar charge transport behaviour (0.11 cm² V⁻¹ s⁻¹ for electrons and 0.045 cm² V⁻¹ s⁻¹ for holes) on FOPA-modified substrates.

Original language	English (US)
Pages (from-to)	545-547
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	5
DOIs	https://doi.org/10.1039/c3cc48037b
State	Published - Dec 10 2014

Publisher link

10.1039/c3cc48037b

Find It

Find It at U of M Libraries

Cite this

@article{e59e940d0166400eaf9721c7ae3b1580,

title = "Cyanated isoindigos for n-type and ambipolar organic thin film transistors",

abstract = "A set of three core-cyanated isoindigos was synthesized by palladium-catalyzed cyanation of core-brominated isoindigos. With decreased LUMO level to −3.88 eV, the dicyanated isoindigo 5 showed ambient-stable electron mobility up to 0.044 cm2 V−1 s−1 in OTFTs with SAMs of TPA, while it exhibited ambipolar charge transport behaviour (0.11 cm2 V−1 s−1 for electrons and 0.045 cm2 V−1 s−1 for holes) on FOPA-modified substrates.",

author = "Wan Yue and Tao He and Matthias Stolte and Marcel Gs{\"a}nger and Frank W{\"u}rthner",

year = "2014",

month = dec,

day = "10",

doi = "10.1039/c3cc48037b",

language = "English (US)",

volume = "50",

pages = "545--547",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Cyanated isoindigos for n-type and ambipolar organic thin film transistors

AU - Yue, Wan

AU - He, Tao

AU - Stolte, Matthias

AU - Gsänger, Marcel

AU - Würthner, Frank

PY - 2014/12/10

Y1 - 2014/12/10

N2 - A set of three core-cyanated isoindigos was synthesized by palladium-catalyzed cyanation of core-brominated isoindigos. With decreased LUMO level to −3.88 eV, the dicyanated isoindigo 5 showed ambient-stable electron mobility up to 0.044 cm2 V−1 s−1 in OTFTs with SAMs of TPA, while it exhibited ambipolar charge transport behaviour (0.11 cm2 V−1 s−1 for electrons and 0.045 cm2 V−1 s−1 for holes) on FOPA-modified substrates.

AB - A set of three core-cyanated isoindigos was synthesized by palladium-catalyzed cyanation of core-brominated isoindigos. With decreased LUMO level to −3.88 eV, the dicyanated isoindigo 5 showed ambient-stable electron mobility up to 0.044 cm2 V−1 s−1 in OTFTs with SAMs of TPA, while it exhibited ambipolar charge transport behaviour (0.11 cm2 V−1 s−1 for electrons and 0.045 cm2 V−1 s−1 for holes) on FOPA-modified substrates.

UR - http://www.scopus.com/inward/record.url?scp=84890371888&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84890371888&partnerID=8YFLogxK

U2 - 10.1039/c3cc48037b

DO - 10.1039/c3cc48037b

M3 - Article

AN - SCOPUS:84890371888

SN - 1359-7345

VL - 50

SP - 545

EP - 547

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Cyanated isoindigos for n-type and ambipolar organic thin film transistors

Abstract

Publisher link

Find It

Other files and links

Fingerprint

Cite this