The title compounds, (N-methyl-N-phenylamino)(N-methyl-N-phenylcarbamoyl)sulfide, C15H16N2OS, (I), and (N-methyl-N-phenylamino)(N-methyl-N-phenylcarbamoyl)disulfane, C15H16N2OS2, (II), are stable derivatives of (chlorocarbonyl)sulfenyl chloride and (chlorocarbonyl)disulfanyl chloride, respectively. The torsion angle about the S - S bond in (II) is -92.62 (6)°, which is close to the theoretical value of 90°. In the crystal of (II), non-classical intermolecular C - H⋯O hydrogen bonds form centrosymmetric cyclic dimers [graph set R22(10)], while inter-dimer C - H⋯S interactions generate chains extending along the b axis.
|Original language||English (US)|
|Number of pages||4|
|Journal||Acta Crystallographica Section E: Crystallographic Communications|
|State||Published - 2015|
- crystal structure
- hydrogen bonding
- organosulfur chemistry