The title compound, C14H16N2S3, crystallized with two independent molecules [(1a) and (1b)] in the asymmetric unit. Both molecules display a pseudo-trans conformation. The two consecutive S-S bond lengths of the trisulfane unit of molecule (1a) are 2.06 (3) and 2.08 (3) Å, and 2.08 (3) and 2.07 (2) Å for molecule (1b). Torsion angles about each of the two S-S bonds are 86.6 (2) and 87.0 (2)° for (1a), and -84.6 (2) and -85.9 (2)° for (1b). The core atoms, viz. the N-S-S-S-N moiety, of the two molecules superimpose well if one is inverted on the other, but the phenyl groups do not. Thus, the two units are essentially conformational enantiomers. In molecule (1a), the two phenyl rings are inclined to one another by 86.7 (3)°, and in molecule (1b), by 81.1 (3)°. In the crystal, molecules are linked via C-H⋯π interactions, forming sheets lying parallel to (010).
|Original language||English (US)|
|Number of pages||4|
|Journal||Acta Crystallographica Section E: Crystallographic Communications|
|State||Published - Jul 2015|
Bibliographical noteFunding Information:
This work was supported by grants from the National Key Research and Development Program of China (grant
2016YFC1200201), the European Commission’s H2020 program under contract number 643476 (http://www. compare-europe.eu), and the Royal Netherlands Academy of Arts and Sciences (project number 530-6CDP23).
- C-H⋯π interactions
- Crystal structure
- Organosulfur compounds