Correlating structure with ferromagnetism in melt-spun Gd 100-xFex

P. M. Shand; D. C. Schmitter; G. Rojas; J. E. Shield; J. Goertzen; A. L. Meyer; T. M. Pekarek; M. J. Kramer; D. L. Leslie-Pelecky

doi:10.1016/j.jallcom.2010.11.185

Correlating structure with ferromagnetism in melt-spun Gd _100-xFe_x

P. M. Shand, D. C. Schmitter, G. Rojas, J. E. Shield, J. Goertzen, A. L. Meyer, T. M. Pekarek, M. J. Kramer, D. L. Leslie-Pelecky

Characterization Facility

Research output: Contribution to journal › Article › peer-review

Abstract

X-ray diffraction and transmission electron microscopy measurements of melt-spun Gd_100-xFe_x (0 x 40) and inert-gas condensed/compacted samples (3.8 x 12.7) reveal a structure of crystalline hcp-Gd grains surrounded by a non-crystalline Gd1-xeffFexeff phase, where x _eff > x is the effective iron concentration within the amorphous region. The two-phase structure is responsible for an unusual dependence of the coercivity on temperature in which non-zero coercivity is observed above the hcp-Gd T_c with a peak near 320 K. The coercivity decreases as the hcp-Gd grains order, then increases with decreasing temperature. This behavior is explained by the presence of magnetically correlated Fe-rich regions.

Original language	English (US)
Pages (from-to)	3000-3005
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	509
Issue number	6
DOIs	https://doi.org/10.1016/j.jallcom.2010.11.185
State	Published - Feb 10 2011

Keywords

Coercivity
Ferromagnetism
Gadolinium-iron alloy
Nanocrystalline

Access

10.1016/j.jallcom.2010.11.185

Fingerprint Dive into the research topics of 'Correlating structure with ferromagnetism in melt-spun Gd <sub>100-x</sub>Fe<sub>x</sub>'. Together they form a unique fingerprint.

Cite this

@article{9dd99c0b6e46420baa5eab6234b5a254,

title = "Correlating structure with ferromagnetism in melt-spun Gd 100-xFex",

abstract = "X-ray diffraction and transmission electron microscopy measurements of melt-spun Gd100-xFex (0 x 40) and inert-gas condensed/compacted samples (3.8 x 12.7) reveal a structure of crystalline hcp-Gd grains surrounded by a non-crystalline Gd1-xeffFexeff phase, where x eff > x is the effective iron concentration within the amorphous region. The two-phase structure is responsible for an unusual dependence of the coercivity on temperature in which non-zero coercivity is observed above the hcp-Gd Tc with a peak near 320 K. The coercivity decreases as the hcp-Gd grains order, then increases with decreasing temperature. This behavior is explained by the presence of magnetically correlated Fe-rich regions.",

keywords = "Coercivity, Ferromagnetism, Gadolinium-iron alloy, Nanocrystalline",

author = "Shand, {P. M.} and Schmitter, {D. C.} and G. Rojas and Shield, {J. E.} and J. Goertzen and Meyer, {A. L.} and Pekarek, {T. M.} and Kramer, {M. J.} and Leslie-Pelecky, {D. L.}",

year = "2011",

month = feb,

day = "10",

doi = "10.1016/j.jallcom.2010.11.185",

language = "English (US)",

volume = "509",

pages = "3000--3005",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier BV",

number = "6",

}

TY - JOUR

T1 - Correlating structure with ferromagnetism in melt-spun Gd 100-xFex

AU - Shand, P. M.

AU - Schmitter, D. C.

AU - Rojas, G.

AU - Shield, J. E.

AU - Goertzen, J.

AU - Meyer, A. L.

AU - Pekarek, T. M.

AU - Kramer, M. J.

AU - Leslie-Pelecky, D. L.

PY - 2011/2/10

Y1 - 2011/2/10

N2 - X-ray diffraction and transmission electron microscopy measurements of melt-spun Gd100-xFex (0 x 40) and inert-gas condensed/compacted samples (3.8 x 12.7) reveal a structure of crystalline hcp-Gd grains surrounded by a non-crystalline Gd1-xeffFexeff phase, where x eff > x is the effective iron concentration within the amorphous region. The two-phase structure is responsible for an unusual dependence of the coercivity on temperature in which non-zero coercivity is observed above the hcp-Gd Tc with a peak near 320 K. The coercivity decreases as the hcp-Gd grains order, then increases with decreasing temperature. This behavior is explained by the presence of magnetically correlated Fe-rich regions.

AB - X-ray diffraction and transmission electron microscopy measurements of melt-spun Gd100-xFex (0 x 40) and inert-gas condensed/compacted samples (3.8 x 12.7) reveal a structure of crystalline hcp-Gd grains surrounded by a non-crystalline Gd1-xeffFexeff phase, where x eff > x is the effective iron concentration within the amorphous region. The two-phase structure is responsible for an unusual dependence of the coercivity on temperature in which non-zero coercivity is observed above the hcp-Gd Tc with a peak near 320 K. The coercivity decreases as the hcp-Gd grains order, then increases with decreasing temperature. This behavior is explained by the presence of magnetically correlated Fe-rich regions.

KW - Coercivity

KW - Ferromagnetism

KW - Gadolinium-iron alloy

KW - Nanocrystalline

UR - http://www.scopus.com/inward/record.url?scp=78651353760&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78651353760&partnerID=8YFLogxK

U2 - 10.1016/j.jallcom.2010.11.185

DO - 10.1016/j.jallcom.2010.11.185

M3 - Article

AN - SCOPUS:78651353760

VL - 509

SP - 3000

EP - 3005

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

IS - 6

ER -