Correlating solvent dynamics and chemical reaction rates using binary solvent mixtures and two-dimensional infrared spectroscopy

Keyphrases

• Two-dimensional Infrared Spectroscopy 100%
• Chemical Reaction Rate 100%
• Solvent Dynamics 100%
• Vaska's Complex 100%
• Binary Solvent 100%
• Dynamic Reaction 100%
• Benzene 40%
• Benzyl Alcohol 40%
• Chloroform 40%
• Two-dimensional Infrared 40%
• FTIR Spectra 40%
• Alcohol 20%
• Product State 20%
• Line Shape 20%
• Chemical Reactivity 20%
• Mixed Solvent 20%
• Carbonyl 20%
• Mole Fraction 20%
• Strong Correlation 20%
• Oxygenation 20%
• Broadening Mechanisms 20%
• Second-order Rate Constant 20%
• Carbonyl Ligands 20%
• Spectral Diffusion 20%
• Alcohol Mixture 20%
• Frequency-frequency Correlation Function 20%
• Linear Spectrum 20%
• Homogeneous Linewidth 20%

Chemistry

• Two-Dimensional Infrared Spectroscopy 100%
• Rate Constant 100%
• Solvent Mixture 100%
• Fourier Transform Infrared Spectroscopy 50%
• Benzyl Alcohol 50%
• Chloroform 50%
• Benzene 50%
• Chemical Reactivity 25%
• Lineshape 25%
• Linewidth 25%