Abstract
A concise copper(I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1207-1210 |
| Number of pages | 4 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 355 |
| Issue number | 6 |
| DOIs | |
| State | Published - Apr 15 2013 |
| Externally published | Yes |
Keywords
- Schmidt rearrangement
- azides
- copper
- dehydrogenation
- nitriles
- oxidation
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