Copper-catalyzed oxidative transformation of aryl propargylic azides to aryl propiolonitriles

Teng Wang, Hang Yin, Ning Jiao

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

A concise copper(I)-catalyzed oxidative transformation of aryl propargyl azides to aryl propiolonitriles has been developed. Aryl propiolonitrile derivatives can be obtained in moderate to good yields by this strategy. An oxidative Schmidt rearrangement is involved in this transformation.

Original languageEnglish (US)
Pages (from-to)1207-1210
Number of pages4
JournalAdvanced Synthesis and Catalysis
Volume355
Issue number6
DOIs
StatePublished - Apr 15 2013

Keywords

  • Schmidt rearrangement
  • azides
  • copper
  • dehydrogenation
  • nitriles
  • oxidation

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