Copper and silver benzoate and aryl complexes and their implications for oxidative decarboxylative coupling reactions

Andreas Baur; Katelyn A. Bustin; Ellen Aguilera; Jeffrey L. Petersen; Jessica M. Hoover

doi:10.1039/c6qo00678g

Copper and silver benzoate and aryl complexes and their implications for oxidative decarboxylative coupling reactions

Andreas Baur, Katelyn A. Bustin, Ellen Aguilera, Jeffrey L. Petersen, Jessica M. Hoover

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

The synthesis and reactivity of phenanthroline-ligated copper and silver benzoate and aryl complexes are reported. The commonly proposed copper(i) and silver(i) aryl species are shown to be unlikely intermediates in the oxidative decarboxylative coupling reaction. Instead, the copper(ii) benzoate undergoes decarboxylative coupling suggesting an unexpected copper(ii) based pathway.

Original language	English (US)
Pages (from-to)	519-524
Number of pages	6
Journal	Organic Chemistry Frontiers
Volume	4
Issue number	4
DOIs	https://doi.org/10.1039/c6qo00678g
State	Published - Apr 2017
Externally published	Yes

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© the Partner Organisations 2017.

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abstract = "The synthesis and reactivity of phenanthroline-ligated copper and silver benzoate and aryl complexes are reported. The commonly proposed copper(i) and silver(i) aryl species are shown to be unlikely intermediates in the oxidative decarboxylative coupling reaction. Instead, the copper(ii) benzoate undergoes decarboxylative coupling suggesting an unexpected copper(ii) based pathway.",

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T1 - Copper and silver benzoate and aryl complexes and their implications for oxidative decarboxylative coupling reactions

AU - Baur, Andreas

AU - Bustin, Katelyn A.

AU - Aguilera, Ellen

AU - Petersen, Jeffrey L.

AU - Hoover, Jessica M.

PY - 2017/4

Y1 - 2017/4

N2 - The synthesis and reactivity of phenanthroline-ligated copper and silver benzoate and aryl complexes are reported. The commonly proposed copper(i) and silver(i) aryl species are shown to be unlikely intermediates in the oxidative decarboxylative coupling reaction. Instead, the copper(ii) benzoate undergoes decarboxylative coupling suggesting an unexpected copper(ii) based pathway.

AB - The synthesis and reactivity of phenanthroline-ligated copper and silver benzoate and aryl complexes are reported. The commonly proposed copper(i) and silver(i) aryl species are shown to be unlikely intermediates in the oxidative decarboxylative coupling reaction. Instead, the copper(ii) benzoate undergoes decarboxylative coupling suggesting an unexpected copper(ii) based pathway.

UR - https://www.scopus.com/pages/publications/85016403337

UR - https://www.scopus.com/inward/citedby.url?scp=85016403337&partnerID=8YFLogxK

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DO - 10.1039/c6qo00678g

M3 - Article

AN - SCOPUS:85016403337

SN - 2052-4110

VL - 4

SP - 519

EP - 524

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 4

ER -

Copper and silver benzoate and aryl complexes and their implications for oxidative decarboxylative coupling reactions

Abstract

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