Abstract
A series of defined iron-hydrogen complexes was prepared in a straightforward one-pot approach. The structure and electronic properties of such complexes were investigated by means of quantum-chemical analysis. These new complexes were then applied in the dehydrogenative silylation of methanol. The complex (dppp)(CO)(NO)FeH showed a remarkable activity with a TOF of more than 600000 h-1 of pure hydrogen gas within seconds.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2140-2147 |
| Number of pages | 8 |
| Journal | Chemistry - An Asian Journal |
| Volume | 9 |
| Issue number | 8 |
| DOIs | |
| State | Published - Aug 2014 |
Keywords
- catalysis
- hydrogen
- iron
- organometallic complexes
- silylation
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