Cooperative catalysis: Electron-rich F-H complexes and DMAP, a successful "joint venture" for ultrafast hydrogen production

Susanne Rommel; Lara Hettmanczyk; Johannes E.M.N. Klein; Bernd Plietker

doi:10.1002/asia.201402142

Cooperative catalysis: Electron-rich F-H complexes and DMAP, a successful "joint venture" for ultrafast hydrogen production

Susanne Rommel, Lara Hettmanczyk, Johannes E.M.N. Klein, Bernd Plietker

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A series of defined iron-hydrogen complexes was prepared in a straightforward one-pot approach. The structure and electronic properties of such complexes were investigated by means of quantum-chemical analysis. These new complexes were then applied in the dehydrogenative silylation of methanol. The complex (dppp)(CO)(NO)FeH showed a remarkable activity with a TOF of more than 600000 h^-1 of pure hydrogen gas within seconds.

Original language	English (US)
Pages (from-to)	2140-2147
Number of pages	8
Journal	Chemistry - An Asian Journal
Volume	9
Issue number	8
DOIs	https://doi.org/10.1002/asia.201402142
State	Published - Aug 2014

Keywords

catalysis
hydrogen
iron
organometallic complexes
silylation

Publisher link

10.1002/asia.201402142

Find It

Find It at U of M Libraries

Cite this

@article{aa461b8deeff461c90612b35bbb1bcde,

title = "Cooperative catalysis: Electron-rich F-H complexes and DMAP, a successful {"}joint venture{"} for ultrafast hydrogen production",

abstract = "A series of defined iron-hydrogen complexes was prepared in a straightforward one-pot approach. The structure and electronic properties of such complexes were investigated by means of quantum-chemical analysis. These new complexes were then applied in the dehydrogenative silylation of methanol. The complex (dppp)(CO)(NO)FeH showed a remarkable activity with a TOF of more than 600000 h-1 of pure hydrogen gas within seconds.",

keywords = "catalysis, hydrogen, iron, organometallic complexes, silylation",

author = "Susanne Rommel and Lara Hettmanczyk and Klein, {Johannes E.M.N.} and Bernd Plietker",

year = "2014",

month = aug,

doi = "10.1002/asia.201402142",

language = "English (US)",

volume = "9",

pages = "2140--2147",

journal = "Chemistry - An Asian Journal",

issn = "1861-4728",

publisher = "John Wiley and Sons Ltd",

number = "8",

}

TY - JOUR

T1 - Cooperative catalysis

T2 - Electron-rich F-H complexes and DMAP, a successful "joint venture" for ultrafast hydrogen production

AU - Rommel, Susanne

AU - Hettmanczyk, Lara

AU - Klein, Johannes E.M.N.

AU - Plietker, Bernd

PY - 2014/8

Y1 - 2014/8

N2 - A series of defined iron-hydrogen complexes was prepared in a straightforward one-pot approach. The structure and electronic properties of such complexes were investigated by means of quantum-chemical analysis. These new complexes were then applied in the dehydrogenative silylation of methanol. The complex (dppp)(CO)(NO)FeH showed a remarkable activity with a TOF of more than 600000 h-1 of pure hydrogen gas within seconds.

AB - A series of defined iron-hydrogen complexes was prepared in a straightforward one-pot approach. The structure and electronic properties of such complexes were investigated by means of quantum-chemical analysis. These new complexes were then applied in the dehydrogenative silylation of methanol. The complex (dppp)(CO)(NO)FeH showed a remarkable activity with a TOF of more than 600000 h-1 of pure hydrogen gas within seconds.

KW - catalysis

KW - hydrogen

KW - iron

KW - organometallic complexes

KW - silylation

UR - http://www.scopus.com/inward/record.url?scp=84905234319&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84905234319&partnerID=8YFLogxK

U2 - 10.1002/asia.201402142

DO - 10.1002/asia.201402142

M3 - Article

C2 - 24807477

AN - SCOPUS:84905234319

SN - 1861-4728

VL - 9

SP - 2140

EP - 2147

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 8

ER -

Cooperative catalysis: Electron-rich F-H complexes and DMAP, a successful "joint venture" for ultrafast hydrogen production

Abstract

Keywords

Publisher link

Find It

Other files and links

Fingerprint

Cite this