Cooperative catalysis approach to intramolecular hydroacylation

Evgeny V. Beletskiy, Sudheer Chava, Christopher J Douglas

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

Prior examples of hydroacylation to form six- and seven-membered ring ketones require either embedded chelating groups or other substrate design strategies to circumvent competitive aldehyde decarbonylation. A cooperative catalysis strategy enabled intramolecular hydroacylation of disubstituted alkenes to form seven- and six-membered rings without requiring substrate-embedded chelating groups.

Original languageEnglish (US)
Pages (from-to)5884-5893
Number of pages10
JournalJournal of Organic Chemistry
Volume77
Issue number14
DOIs
StatePublished - Jul 20 2012

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