Controlled Synthesis of an Alternating Donor-Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation

Alexander D. Todd; Christopher W. Bielawski

doi:10.1021/acsmacrolett.5b00505

Controlled Synthesis of an Alternating Donor-Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation

Alexander D. Todd, Christopher W. Bielawski

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Kumada catalyst-transfer polycondensation was used to synthesize poly(5,6-difluorobenzotriazole-alt-4-hexylthiophene) (PFBTzHT), an alternating donor-acceptor conjugated polymer, in a controlled manner. Through a series of kinetic studies, a linear relationship between the monomer conversion and the molecular weight of the resulting polymer was observed while maintaining narrow polydispersities (Ds ≤ 1.4). Moreover, the M_n displayed a linear relationship with the initial monomer-to-catalyst feed ratio, and polymers with M_ns up to 25 kDa were successfully synthesized. All-conjugated block copolymers containing segments of PFBTzHT and poly(3-hexylthiophene) (P3HT) were also obtained in various compositions (30-70% P3HT) via sequential monomer addition in a single vessel.

Original language	English (US)
Pages (from-to)	1254-1258
Number of pages	5
Journal	ACS Macro Letters
Volume	4
Issue number	11
DOIs	https://doi.org/10.1021/acsmacrolett.5b00505
State	Published - Oct 27 2015

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

Publisher link

10.1021/acsmacrolett.5b00505

Find It

Find It at U of M Libraries

Cite this

@article{2dd4386260834099a2eb6076eb7ff3fd,

title = "Controlled Synthesis of an Alternating Donor-Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation",

abstract = "Kumada catalyst-transfer polycondensation was used to synthesize poly(5,6-difluorobenzotriazole-alt-4-hexylthiophene) (PFBTzHT), an alternating donor-acceptor conjugated polymer, in a controlled manner. Through a series of kinetic studies, a linear relationship between the monomer conversion and the molecular weight of the resulting polymer was observed while maintaining narrow polydispersities (Ds ≤ 1.4). Moreover, the Mn displayed a linear relationship with the initial monomer-to-catalyst feed ratio, and polymers with Mns up to 25 kDa were successfully synthesized. All-conjugated block copolymers containing segments of PFBTzHT and poly(3-hexylthiophene) (P3HT) were also obtained in various compositions (30-70% P3HT) via sequential monomer addition in a single vessel.",

author = "Todd, {Alexander D.} and Bielawski, {Christopher W.}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = oct,

day = "27",

doi = "10.1021/acsmacrolett.5b00505",

language = "English (US)",

volume = "4",

pages = "1254--1258",

journal = "ACS Macro Letters",

issn = "2161-1653",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Controlled Synthesis of an Alternating Donor-Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation

AU - Todd, Alexander D.

AU - Bielawski, Christopher W.

PY - 2015/10/27

Y1 - 2015/10/27

N2 - Kumada catalyst-transfer polycondensation was used to synthesize poly(5,6-difluorobenzotriazole-alt-4-hexylthiophene) (PFBTzHT), an alternating donor-acceptor conjugated polymer, in a controlled manner. Through a series of kinetic studies, a linear relationship between the monomer conversion and the molecular weight of the resulting polymer was observed while maintaining narrow polydispersities (Ds ≤ 1.4). Moreover, the Mn displayed a linear relationship with the initial monomer-to-catalyst feed ratio, and polymers with Mns up to 25 kDa were successfully synthesized. All-conjugated block copolymers containing segments of PFBTzHT and poly(3-hexylthiophene) (P3HT) were also obtained in various compositions (30-70% P3HT) via sequential monomer addition in a single vessel.

AB - Kumada catalyst-transfer polycondensation was used to synthesize poly(5,6-difluorobenzotriazole-alt-4-hexylthiophene) (PFBTzHT), an alternating donor-acceptor conjugated polymer, in a controlled manner. Through a series of kinetic studies, a linear relationship between the monomer conversion and the molecular weight of the resulting polymer was observed while maintaining narrow polydispersities (Ds ≤ 1.4). Moreover, the Mn displayed a linear relationship with the initial monomer-to-catalyst feed ratio, and polymers with Mns up to 25 kDa were successfully synthesized. All-conjugated block copolymers containing segments of PFBTzHT and poly(3-hexylthiophene) (P3HT) were also obtained in various compositions (30-70% P3HT) via sequential monomer addition in a single vessel.

UR - http://www.scopus.com/inward/record.url?scp=84947219361&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84947219361&partnerID=8YFLogxK

U2 - 10.1021/acsmacrolett.5b00505

DO - 10.1021/acsmacrolett.5b00505

M3 - Article

AN - SCOPUS:84947219361

SN - 2161-1653

VL - 4

SP - 1254

EP - 1258

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 11

ER -

Controlled Synthesis of an Alternating Donor-Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Cite this