Control of magnetite primary particle size in aqueous dispersions of nanoclusters for high magnetic susceptibilities

Ki Youl Yoon, Zheng Xue, Yunping Fei, Jae Ho Lee, Victoria Cheng, Hitesh G. Bagaria, Chun Huh, Steven L. Bryant, Seong Deok Kong, Vincent W. Ngo, Amir Reza Rahmani, Mohsen Ahmadian, Christopher J. Ellison, Keith P. Johnston

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Aqueous dispersions of iron oxide nanoparticles with a high initial magnetic susceptibility (χi) are of interest as contrast agents in electromagnetic tomography. Nanoclusters composed of iron oxide primary particles were formed by co-precipitation of Fe(II) and Fe(III) chlorides at alkaline conditions and high temperature of 95. °C. Two-step addition of citrate was used to produce large primary particles and then stabilize the nanoclusters. The size of the primary particles was tuned from 5. nm to 15. nm by varying the citrate/iron precursor ratio during the normal phase hydrolysis reaction, while the second iteration of citrate stabilized the nanoclusters with hydrodynamic diameters of 30-75. nm. The crystallinity of the iron oxide nanoparticles was promoted by annealing at 95. °C and systematically studied with Superconducting Quantum Interference Device (SQUID), Vibrating Sample Magnetometer (VSM), Transmission Electron Microscopy (TEM) and X-ray Diffraction (XRD). The dependence of χi was examined over a range of low volume fractions (0.005. <. θ<. 0.02) to understand the magnetic behavior of dispersions. The χi of the dispersions increased markedly with the size and concentration of the constituent primary particles, reaching an unusually high value of 0.85 at 1.6% v/v for 15. nm primary particles, which is 2-3 times higher than that for typical commercial ferrofluids. The high χi values are favored by the high crystallinity and the large magnetic diameter of 9.3. nm, indicating a relatively thin surface nonmagnetic layer where the spin orientations are disordered.

Original languageEnglish (US)
Pages (from-to)359-367
Number of pages9
JournalJournal of Colloid And Interface Science
Volume462
DOIs
StatePublished - Jan 15 2016

Bibliographical note

Funding Information:
This work was supported by the Advanced Energy Consortium. Member companies include Shell, Petrobras, Schlumberger, BP America Inc., Statoil, Total, the BG Group and Repsol. Additional support was received from Conoco-Phillips, Baker-Hughes, Halliburton, Marathon Oil Corp. and Occidental Oil and Gas. We are also grateful for funds from Gulf of Mexico Research Initiative and the Welch Foundation ( F1319 ). We thank William Hardin for assistance with XRD analysis and John Ullo for many useful discussions.

Publisher Copyright:
© 2015.

Keywords

  • Aqueous dispersion
  • Colloidal stability
  • Electromagnetic imaging
  • Magnetic susceptibility
  • Magnetite
  • Superparamagnetic nanoparticles

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