Construction of the steroid framework via a functionalized macrocyclic compound

Gerald Dyker, Peter Grundt

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

A palladium-catalyzed intramolecular coupling process leads to a functionalized macrocycle suitable for a double transannular cyclization. The resulting steroid framework, and its stereo- and regioisomers, are identified by analysis of the NMR-spectroscopic data.

Original languageEnglish (US)
Pages (from-to)323-327
Number of pages5
JournalEuropean Journal of Organic Chemistry
Issue number1
DOIs
StatePublished - Jan 1999

Keywords

  • Heck reaction
  • Macrocycles
  • Robinson-type annulation
  • Steroids

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