Conformations of a tethered membrane: Crumpling in graphitic oxide?

M. S. Spector, E. Naranjo, S. Chiruvolu, J. A. Zasadzinski

Research output: Contribution to journalArticlepeer-review

102 Scopus citations

Abstract

We have used freeze-fracture electron microscopy and static light scattering to study the conformations of two-dimensional sheets of graphitic oxide suspended in aqueous solution. Electron micrographs show the graphite sheets are flat with some curling at the edges. Scattering experiments yield a fractal dimension of 2.15 (0.06). Lowering the solvent polarity with acetone enhances the intramembrane affinity and leads to a compact structure. Under no conditions did we find a crumpled phase, which had been hypothesized as possible for 2D tethered membranes.

Original languageEnglish (US)
Pages (from-to)2867-2870
Number of pages4
JournalPhysical review letters
Volume73
Issue number21
DOIs
StatePublished - 1994
Externally publishedYes

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